Hunter P Hickox
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Explore the profile of Hunter P Hickox including associated specialties, affiliations and a list of published articles.
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7
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17
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Recent Articles
1.
Hickox H, Wang Y, Luedecke K, Xie Y, Wei P, Carrillo D, et al.
Dalton Trans
. 2017 Nov;
47(1):41-44.
PMID: 29168513
Reaction of 2-bromo-1,3,2-diazaborole (1) with excess BBr induces 1,2-hydrogen migration, giving 1,3,2-diazaborole-derived carbene complexes of boron bromide (2). Compound 2 exists in a dynamic solution equilibrium with 1. The H...
2.
Wang Y, Hickox H, Xie Y, Wei P, Schaefer 3rd H, Robinson G
J Am Chem Soc
. 2017 Nov;
139(45):16109-16112.
PMID: 29091731
Reaction of thiolate 1 with carbene-stabilized diiodo-bis-silylene (2) (in a 2:1 ratio) in THF unexpectedly gives both the first five-membered, sulfur-containing, zwitterionic silylene ring (3) via insertion of the "Si"...
3.
Wang Y, Hickox H, Xie Y, Wei P, Blair S, Johnson M, et al.
J Am Chem Soc
. 2017 May;
139(20):6859-6862.
PMID: 28482154
Sulfurization of anionic N-heterocyclic dicarbene, [:C{[N(2,6-PrCH)]CHCLi}] (2), with elemental sulfur (in a 1:2 ratio) in EtO at low temperature gives 3 by inserting two sulfur atoms into the Li-C (i.e.,...
4.
Wang Y, Hickox H, Wei P, Robinson G
Dalton Trans
. 2017 Feb;
46(17):5508-5512.
PMID: 28229146
While the 1 : 1 reaction of C4-trichlorosilyl-functionalized N-heterocyclic carbene (NHC) (2) with [(η-CHLi)Fe][TMEDA] (3) gives C4-sila[1]ferrocenophane-substituted NHC (4), C4-ferrocenylsilyl-bridged bis-NHC (6) is synthesized by combining 3 with C4-chlorodimethylsilyl-functionalized NHC...
5.
Hickox H, Wang Y, Xie Y, Wei P, Schaefer 3rd H, Robinson G
J Am Chem Soc
. 2016 Jul;
138(31):9799-802.
PMID: 27466944
While reaction of carbene-stabilized disilicon L:Si═Si:L (L: = C{N(2,6-(i)Pr2C6H3)CH}2) (8) with HCl·NC5H5 results in carbene-stabilized Si2Cl2 (2) and substituted 1H-imidazole (9), combination of the corresponding Fe(CO)4-modified disilicon carbene complex L:Si═Si[Fe(CO)4]:L...
6.
Wang Y, Hickox H, Xie Y, Wei P, Cui D, Walter M, et al.
Chem Commun (Camb)
. 2016 Apr;
52(33):5746-8.
PMID: 27046462
Reaction of carbene-stabilized diphosphorus, L:P-P:L (5) (L: = :C{N(2,6-Pr(i)2C6H3)CH}2) with pyridine hydrochloride yields [L:(H)P-P:L]Cl (6), a salt containing the HP2(+) cation--the elusive phosphorus analogue of the well known diazonium cation,...
7.
Hickox H, Wang Y, Xie Y, Chen M, Wei P, Schaefer 3rd H, et al.
Angew Chem Int Ed Engl
. 2015 Jun;
54(35):10267-70.
PMID: 26037780
Reaction of carbene-stabilized disilicon (1) with Fe(CO)5 gives the 1:1 adduct L:Si=Si[Fe(CO)4 ]:L (L:=C{N(2,6-Pr(i) 2 C6 H3 )CH}2 ) (2) at room temperature. At raised temperature, however, 2 may react...