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Harrison D Root

Explore the profile of Harrison D Root including associated specialties, affiliations and a list of published articles. Areas
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Articles 15
Citations 37
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Recent Articles
1.
Shaw T, Jones Z, Adelman S, Anderson N, Bowes E, Bauer E, et al.
Chem Sci . 2024 Aug; 15(32):12754-12764. PMID: 39148769
Recent advances enabled the discovery of heterometallic molecules for many metals: main group, d-block, lanthanides, and some actinides (U, Th). These complexes have at least two different metals joined by...
2.
Rimsza J, Duwal S, Root H
ACS Omega . 2024 Jul; 9(26):29025-29034. PMID: 38973899
Efficient carbon capture requires engineered porous systems that selectively capture CO and have low energy regeneration pathways. Porous liquids (PLs), solvent-based systems containing permanent porosity through the incorporation of a...
3.
Root H, Thiabaud G, Sessler J
Front Chem Sci Eng . 2023 Oct; 14(1):19-27. PMID: 37786429
We report here a water-soluble metal cation sensor system based on the as-prepared or reduced form of an expanded porphyrin, texaphyrin. Upon metal complexation, a change in the redox state...
4.
DiMucci I, Root H, Jones Z, Kozimor S, MacInnes M, Miller J, et al.
Chem Commun (Camb) . 2022 Sep; 58(78):10961-10964. PMID: 36083292
Plutonium-based technologies would benefit if chemical hazards for purifying plutonium were reduced. One critical processing step where improvements could be impactful is the adjustment of plutonium oxidation-states during separations. This...
5.
Rice N, Dalodiere E, Adelman S, Jones Z, Kozimor S, Mocko V, et al.
Inorg Chem . 2022 Aug; 61(33):12948-12953. PMID: 35939562
Historic perspectives describing f-elements as being redox "inactive" are fading. Researchers continue to discover new oxidation states that are not as inaccessible as once assumed for actinides and lanthanides. Inspired...
6.
Aldrich K, Popov I, Root H, Batista E, Greer S, Kozimor S, et al.
Dalton Trans . 2022 Jun; 51(26):9994-10005. PMID: 35739082
Developing chelators that strongly and selectively bind rare-earth elements (Sc, Y, La, and lanthanides) represents a longstanding fundamental challenge in inorganic chemistry. Solving these challenges is becoming more important because...
7.
Bacchella C, Brewster 2nd J, Bahring S, DellAcqua S, Root H, Thiabaud G, et al.
Molecules . 2020 Nov; 25(21). PMID: 33143109
The peroxidase activity of hemin-peptide complexes remains a potential factor in oxidative damage relevant to neurodegeneration. Here, we present the effect of temperature, ionic strength, and pH relevant to pathophysiological...
8.
Lee J, Root H, Ali R, An W, Lynch V, Bahring S, et al.
J Am Chem Soc . 2020 Oct; 142(46):19579-19587. PMID: 33063999
There is a recognized need in the area of explosives detection for fluorescence-based sensing systems that are capable of not only producing a turn-on response but also generating a distinctive...
9.
Root H, Mangel D, Brewster 2nd J, Zafar H, Samia A, Henkelman G, et al.
Chem Commun (Camb) . 2020 Jul; 56(69):9994-9997. PMID: 32724979
The use of protonation to switch nonaromatic expanded porphyrins to their corresponding anti-aromatic forms has not been widely explored. Here, we show that free-base pyriamethyrin and dipyriamethyrin display nonaromatic character,...
10.
Brewster 2nd J, Root H, Zafar H, Thiabaud G, Sedgwick A, He J, et al.
Molecules . 2020 Mar; 25(6). PMID: 32210058
The reaction between dipyriamethyrin and copper(II) acetate [Cu(OAc)] afforded what is, to our knowledge, the first transition metal-dipyriamethyrin complex. Molecular and electronic characterization of this binuclear Cu(II) complex via EPR,...