Francois Mathey
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Explore the profile of Francois Mathey including associated specialties, affiliations and a list of published articles.
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69
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155
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Recent Articles
1.
Liu Y, Tian R, Duan Z, Mathey F
Dalton Trans
. 2020 Dec;
50(2):476-479.
PMID: 33355316
The coordination chemistry of 1-phosphafulvenes was investigated by employing their [6 + 4] adducts or α-C-bridged biphospholes as a precursor. Unbridged phosphacymantrenes arise from 1-phosphafulvenes via proton abstraction. α-C-bridged biphosphacymantrenes...
2.
Wang J, Wei D, Duan Z, Mathey F
J Am Chem Soc
. 2020 Dec;
142(50):20973-20978.
PMID: 33284022
[1 + 2] cycloaddition is a classical reaction between the electrophilic phosphinidene and an alkene. However, a spatial constraint blocks this well-known reaction and enables an unprecedented chemoselective C(sp)-Ar σ-bond...
3.
Liu Y, Zhang K, Tian R, Duan Z, Mathey F
Org Lett
. 2020 Aug;
22(17):6972-6976.
PMID: 32846086
An unusual chemoselective 1,1-addition of α-C-bridged biphospholes to terminal alkynes is reported. The developed protocol provides simple access to the unknown 1,3-diphosphepines, which has potential applications in the coordination and...
4.
Wang M, Yang T, Tian R, Wei D, Duan Z, Mathey F
Chem Commun (Camb)
. 2020 Jul;
56(67):9707-9710.
PMID: 32699865
Thermolysis of the 1,1'-biphosphirane pentacarbonylmetal complex offers access to 3,4-dihydro-1,2-diphosphete and diphosphorus (P2) intermediates. A control reaction proves that this step-wise reaction is initiated by the dissociation of a W(CO)5...
5.
Yang X, Xu M, Wang J, Liu M, Mathey F, Hua Y, et al.
Org Biomol Chem
. 2020 May;
18(20):3917-3926.
PMID: 32400845
An enantioselective Michael/transesterification tandem reaction of α-hydroxy indanones with ortho-ester chalcones was realized using dinuclear zinc catalysts. A series of enantiomerically pure spiro[indanone-2,3'-isochromane-1-one] derivatives were obtained in good yields with...
6.
Hu W, Li E, Duan Z, Mathey F
J Org Chem
. 2020 May;
85(22):14772-14778.
PMID: 32375482
A simple method to build phospholene derivatives has been achieved in a one-pot reaction with readily available -alkynylaryl bromides and alkylphosphine oxides. This method is also applicable to synthesize P-stereogenic...
7.
Cui H, Li K, Wang Y, Song M, Wang C, Wei D, et al.
Org Biomol Chem
. 2020 May;
18(19):3740-3746.
PMID: 32367104
A copper-catalyzed asymmetric 1,3-dipolar cycloaddition of glycine iminoesters with alkyl substituted 3-methylene-2-oxindoles is described. By using de novo design of P-stereogenic phosphines as ligands, spiro[pyrrolidin-3,3'-oxindole]s are generated in good to...
8.
Xu Y, Jiao C, Li J, Tian R, Duan Z, Mathey F
Org Lett
. 2019 Nov;
21(23):9512-9515.
PMID: 31746615
A short and efficient route to peri-fused heterocycles has been developed. The transition metal in cooperation with the imino directing group cleaves the C-P bond of the phosphirane, followed by...
9.
Wang M, Xu Y, Wei D, Tian R, Duan Z, Mathey F
Chemistry
. 2019 Oct;
25(66):15036-15039.
PMID: 31647591
tert-Butylthiophosphinidene complex [tBuSP-W(CO) ] was generated by dissociation of 1-(tert-butylthio)phosphirane-W(CO) complex under mild conditions. The formation of transient [tBuSP-W(CO) ] was indicated by trapping reactions with 2,3-dimethyl-1,3-butadiene, alkynes, phenanthrene-9,10-dione, and...
10.
Yang X, Liu M, Mathey F, Yang H, Hua Y, Wang M
J Org Chem
. 2019 May;
84(12):7762-7775.
PMID: 31145619
A series of new nonsymmetric semi-azacrown ether ligands were developed and applied to the asymmetric Michael/cyclic keto-imine formation/Friedel-Crafts alkylation reactions of 3-amino oxindole hydrochlorides and β,γ-unsaturated α-keto amides. A diversity...