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Federico Rastrelli

Explore the profile of Federico Rastrelli including associated specialties, affiliations and a list of published articles. Areas
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Citations 271
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Recent Articles
1.
Franco-Ulloa S, Cesari A, Riccardi L, De Biasi F, Rosa-Gastaldo D, Mancin F, et al.
J Phys Chem Lett . 2023 Jul; 14(30):6912-6918. PMID: 37498189
Nanoparticle-assisted nuclear magnetic resonance (NMR) chemosensing exploits monolayer-protected nanoparticles as supramolecular hosts to detect small molecules in complex mixtures via nuclear Overhauser effect experiments with detection limits down to the...
2.
Dalla Valle C, Sandri F, Zecca M, Rastrelli F, Campestrini S, Centomo P
Materials (Basel) . 2023 May; 16(10). PMID: 37241434
A novel synthetic procedure for the functionalisation of styrenic cross-linked polymers with perfluorinated acyl chains has been reported. The effective significant grafting of the fluorinated moieties is supported by {H}-C...
3.
Cesari A, Rosa-Gastaldo D, Pedrini A, Rastrelli F, Dalcanale E, Pinalli R, et al.
Chem Commun (Camb) . 2022 Sep; 58(77):10861-10864. PMID: 36074813
We report a strategy for the realization of NMR chemosensors based on the spontaneous self-assembly of lower rim pyridinium-functionalized tetraphopshonate cavitands on commercial silica nanoparticles. These nanohybrids enable the selective...
4.
De Biasi F, Mascitti B, Kupce E, Rastrelli F
J Magn Reson . 2022 Mar; 338:107190. PMID: 35306453
In the study of small molecule ligands and candidate macromolecular targets, water spins in long-lived association with macromolecules (proteins or nanoparticles) constitute a remarkable source of magnetization that can be...
5.
De Biasi F, Rosa-Gastaldo D, Mancin F, Rastrelli F
Chem Commun (Camb) . 2021 Feb; 57(24):3002-3005. PMID: 33623940
"Nanoparticle-assisted NMR chemosensing" combines magnetization transfer NMR techniques with the recognition abilities of gold nanoparticles (AuNPs) to isolate the NMR spectrum of relevant organic species in mixtures. The efficiency of...
6.
Trzcinski J, Morillas-Becerril L, Scarpa S, Tannorella M, Muraca F, Rastrelli F, et al.
Biomacromolecules . 2020 Dec; 22(2):467-480. PMID: 33347750
Herein we present an innovative approach to produce biocompatible, degradable, and stealth polymeric nanoparticles based on poly(lipoic acid), stabilized by a PEG-ended surfactant. Taking advantage of the well-known thiol-induced polymerization...
7.
De Biasi F, Moro F, Frezzato D, Rastrelli F
Phys Chem Chem Phys . 2020 Sep; 22(37):21383-21392. PMID: 32940299
Micrometric hollow silica spheres can effectively reduce magnetic field inhomogeneities when employed as a stationary phase in the context of NMR chromatography. We here provide a description of the NMR...
8.
De Biasi F, Mancin F, Rastrelli F
Prog Nucl Magn Reson Spectrosc . 2020 May; 117:70-88. PMID: 32471535
Sensing methodologies for the detection of target compounds in mixtures are important in many different contexts, ranging from medical diagnosis to environmental analysis and quality assessment. Ideally, such detection methods...
9.
Dalla Valle C, Zecca M, Rastrelli F, Tubaro C, Centomo P
Polymers (Basel) . 2020 Mar; 12(3). PMID: 32155744
The chemical structure and morphology of a set of sulfonic gel-type poly(styrene-divinylbenzene) resins (2 mol% DVB) prepared with different synthetic approaches were investigated by solid state NMR, Inverse Size Exclusion...
10.
Sun X, Rosa-Gastaldo D, De Biasi F, Rastrelli F, Mancin F
Chempluschem . 2020 Jan; 84(10):1498-1502. PMID: 31943937
A sensing protocol to detect potassium ions in water by H NMR spectroscopy is described. The method exploits the K -modulated affinity of 18-crown-6 functionalized gold nanoparticles towards organic ions,...