Faraj Hasanayn
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Explore the profile of Faraj Hasanayn including associated specialties, affiliations and a list of published articles.
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23
Citations
56
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Recent Articles
1.
Parihar A, Emge T, Hasanayn F, Goldman A
J Am Chem Soc
. 2025 Mar;
PMID: 40078057
We report that the cationic iridium complex (PCP)IrH catalyzes the transfer-dehydrogenation of alkanes to give alkenes and hydrogen isotope exchange (HIE) of alkanes and arenes. Contrary to established selectivity trends...
2.
Barakat M, Elhajj S, Yazji R, Miller A, Hasanayn F
Inorg Chem
. 2024 Jun;
63(26):12133-12145.
PMID: 38901030
The 1,2-insertion reaction of CO into metal-hydride bonds of d-octahedral complexes to give κ--metal-formate products is the key step in various CO reduction schemes and as a result has attracted...
3.
McMillion N, Bruch Q, Chen C, Hasanayn F, Miller A
Dalton Trans
. 2023 Oct;
52(41):15115-15123.
PMID: 37814941
Seven-coordinate rhenium oxo complexes supported by a tetradentate bipyridine carboxamide/carboxamidate ligand are reported. The neutral dicarboxamide Hbpy-da ligand initially coordinates in an L (ONNO) fashion to an octahedral rhenium oxo...
4.
Bhatti T, Kumar A, Parihar A, Moncy H, Emge T, Waldie K, et al.
J Am Chem Soc
. 2023 Aug;
145(33):18296-18306.
PMID: 37552857
The -N-pyridyl-based PCP pincer proligand 3,5-bis(di--butylphosphinomethyl)-2,6-dimethylpyridine (pN-PCP-H) was synthesized and metalated to give the iridium complex (pN-PCP)IrHCl (). In marked contrast with its phenyl-based congeners, e.g., (PCP)IrHCl and derivatives, is...
5.
Hasanayn F, Holland P, Goldman A, Miller A
J Am Chem Soc
. 2023 Feb;
145(8):4326-4342.
PMID: 36796367
The activation of dinitrogen by coordination to transition metal ions is a widely used and promising approach to the utilization of Earth's most abundant nitrogen source for chemical synthesis. End-on...
6.
Espinosa M, Ertem M, Barakat M, Bruch Q, Deziel A, Elsby M, et al.
J Am Chem Soc
. 2022 Sep;
144(39):17939-17954.
PMID: 36130605
The kinetics of hydride transfer from Re(bpy)(CO)H (bpy = 4,4'-R-2,2'-bipyridine; R = OMe, Bu, Me, H, Br, COOMe, CF) to CO and seven different cationic N-heterocycles were determined. Additionally, the...
7.
Gordon B, Lease N, Emge T, Hasanayn F, Goldman A
J Am Chem Soc
. 2022 Feb;
144(9):4133-4146.
PMID: 35224972
The selective functionalization of alkanes and alkyl groups is a major goal of chemical catalysis. Toward this end, a bulky triphosphine with a central secondary phosphino group, bis(2-di--butyl-phosphinophenyl)phosphine (PPP), has...
8.
Yamout L, Ataya M, Hasanayn F, Holland P, Miller A, Goldman A
J Am Chem Soc
. 2021 Jun;
143(26):9744-9757.
PMID: 34180663
Terminal and bridging end-on coordination of N to transition metal complexes offer possibilities for distinct pathways in ammonia synthesis and N functionalization. Here we elucidate the fundamental factors controlling the...
9.
Weber J, Hasanayn F, Fataftah M, Mercado B, Crabtree R, Holland P
Inorg Chem
. 2021 Apr;
60(9):6115-6124.
PMID: 33847125
Bimetallic nitrogen (N) splitting to form metal nitrides is an attractive method for N fixation. Although a growing number of pincer-supported systems can bind and split N, the precise relationship...
10.
Lu Y, Zhang X, Malakar S, Krogh-Jespersen K, Hasanayn F, Goldman A
J Org Chem
. 2020 Jan;
85(5):3020-3028.
PMID: 31990556
Di-isopropylphosphino-substituted pincer-ligated iridium catalysts are found to be significantly more effective for the dehydrogenation of simple tertiary amines to give enamines than the previously reported di--butylphosphino-substituted species. It is also...