Derya Gulcemal
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Explore the profile of Derya Gulcemal including associated specialties, affiliations and a list of published articles.
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19
Citations
57
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Recent Articles
1.
Genc S, Arslan B, Gulcemal D, Gulcemal S, Gunnaz S
Org Biomol Chem
. 2022 Nov;
20(48):9753-9762.
PMID: 36448637
Nickel(II)-salen or nickel(II)-salphen catalyzed α-alkylation of ketones and nitriles with primary alcohols is reported. Various α-alkylated ketones and nitriles were obtained in high yields through a borrowing hydrogen strategy by...
2.
Tabasi N, Genc S, Gulcemal D
Org Biomol Chem
. 2022 Aug;
20(33):6582-6592.
PMID: 35913502
An acceptorless dehydrogenative coupling of primary alcohols to carboxylic acids/carboxylates, esters, and Guerbet alcohols ( both homo- and cross-β-alkylation of the alcohols) in the presence of an N-heterocyclic carbene iridium(I)...
3.
Genc S, Gulcemal S, Gunnaz S, Cetinkaya B, Gulcemal D
Org Lett
. 2021 Jun;
23(13):5229-5234.
PMID: 34143639
A new method for converting terminal epoxides and primary alcohols into α-alkylated ketones under borrowing hydrogen conditions is reported. The procedure involves a one-pot epoxide ring opening and alkylation via...
4.
Genc S, Gulcemal S, Gunnaz S, Cetinkaya B, Gulcemal D
J Org Chem
. 2020 Jun;
85(14):9139-9152.
PMID: 32584037
Under borrowing hydrogen conditions, NHC-iridium(I) catalyzed the direct or one-pot sequential synthesis of α,α-disubstituted ketones the alkylation of secondary alcohols with primary alcohols is reported. Notably, the present approach provides...
5.
Genc S, Arslan B, Gulcemal S, Gunnaz S, Cetinkaya B, Gulcemal D
J Org Chem
. 2019 Apr;
84(10):6286-6297.
PMID: 30986066
Iridium(I) complexes having an imidazol-2-ylidene ligand with benzylic wingtips efficiently catalyzed the β-alkylation of secondary alcohols with primary alcohols and acceptorless dehydrogenative cyclization of 2-aminobenzyl alcohol with ketones through a...
6.
Genc S, Gunnaz S, Cetinkaya B, Gulcemal S, Gulcemal D
J Org Chem
. 2018 Feb;
83(5):2875-2881.
PMID: 29432002
A highly effective and green procedure for the formation of α-alkylated ketones has been disclosed via the reaction of primary alcohols with secondary alcohols and ketones by using [IrCl(COD)(NHC)] complexes...
7.
Aslanipour B, Gulcemal D, Nalbantsoy A, Yusufoglu H, Bedir E
Fitoterapia
. 2017 Aug;
122:26-33.
PMID: 28827003
A new cycloartane sapogenol and a new cycloartane xyloside were isolated from Astragalus karjaginii BORISS along with thirteen known compounds. The structures of the new compounds were established as 3-oxo-6α,16β,24(S),25-tetrahydroxycycloartane...
8.
Gulcemal S, Gulcemal D, Whitehead G, Xiao J
Chemistry
. 2016 Jun;
22(30):10513-22.
PMID: 27321021
A series of new Ir(III) complexes with carbene ligands that contain a range of benzyl wingtip groups have been prepared and fully characterised by NMR spectroscopy, HRMS, elemental analysis and...
9.
Senel G, Gulcemal D, Masullo M, Piacente S, Karayildirim T
Chem Biodivers
. 2014 Mar;
11(3):408-18.
PMID: 24634070
Three new oleanane-type glycosides, 1-3, were isolated from the whole plant of Tremastelma palaestinum (L.) Janchen, along with eight known triterpene glycosides. The structures of the new compounds were established...
10.
Gulcemal D, Masullo M, Alankus-Caliskan O, Piacente S
Fitoterapia
. 2013 Dec;
92:274-9.
PMID: 24321579
Four new oleanane-type triterpene glycosides were isolated from the methanol extract of the roots of Paronychia anatolica subsp. balansae along with three known oleanane-type triterpene glycosides. Structures of the new...