David M Hodgson
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Explore the profile of David M Hodgson including associated specialties, affiliations and a list of published articles.
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Recent Articles
1.
Fleming M, Hodgson D
Beilstein J Org Chem
. 2021 Oct;
17:2385-2389.
PMID: 34621400
α-Lithiated terminal epoxides and -(-butylsulfonyl)aziridines undergo eliminative cross-coupling with α-lithio ethers, to give convergent access to allylic alcohols and allylic amines, respectively. The process can be considered as proceeding by...
2.
Delany P, Mortimer C, Hodgson D
Chem Commun (Camb)
. 2020 Sep;
56(81):12174-12177.
PMID: 32910117
Sn-Li exchange and 'poor man's Hoffmann tests' establish asymmetric trapping of α-lithio-N-(tert-butoxythiocarbonyl) (Botc) azetidine to be controlled by dynamic thermodynamic resolution or dynamic kinetic resolution, depending on the electrophile. Unusually,...
3.
Delany P, Hodgson D
Org Lett
. 2019 Dec;
21(24):9981-9984.
PMID: 31800252
An α-boryl azetidine, obtained by α-lithiation-borylation of -Botc azetidine, undergoes reaction with α-triisopropylbenzoyloxy organolithiums to give homologated boronic esters that can be further oxidized, homologated, arylated, and deprotected to give...
4.
Sintim H, Al Mamari H, Almohseni H, Fegheh-Hassanpour Y, Hodgson D
Beilstein J Org Chem
. 2019 Jul;
15:1194-1202.
PMID: 31293666
(,)-Dimethyl tartrate acetonide in THF/HMPA undergoes deprotonation with LDA and reaction at -78 °C during 12-72 h with a range of alkyl halides, including non-activated substrates, to give single diastereomers...
5.
Fegheh-Hassanpour Y, Arif T, Sintim H, Al Mamari H, Hodgson D
Org Lett
. 2018 Aug;
20(17):5528.
PMID: 30125117
No abstract available.
6.
Almohseni H, Al Mamari H, Valade A, Sintim H, Hodgson D
Chem Commun (Camb)
. 2018 May;
54(42):5354-5356.
PMID: 29741545
The presence of a bromide substituent, instead of a hydrogen or methyl group, on a carbon-carbon double bond, protects the alkene from addition reactions when exposed to trifluoroacetic acid. This...
7.
Fegheh-Hassanpour Y, Ebrahim F, Arif T, Sintim H, Claridge T, Amin N, et al.
Org Biomol Chem
. 2018 Apr;
16(16):2876-2884.
PMID: 29611856
The scope and limitations are described of reacting unsaturated tosylhydrazones with O3 followed by Et3N for the generation of 1,4- and 1,5-diazocarbonyl systems. Tosylhydrazones, from tosylhydrazide condensation with readily available...
8.
Li Y, Jackson K, Charlton A, Le Neve-Foster B, Khurshid A, Rudy H, et al.
J Org Chem
. 2017 Sep;
82(19):10479-10488.
PMID: 28952729
Quantum chemical studies of C-ethylation of 1-methyl- and 1,4,4-trimethyl-tropane-derived enamines predict good (89:11 er, B3LYP) and high (98:2 er, B3LYP) levels, respectively, of asymmetric induction in the resulting α-alkylated aldehydes....
9.
Ribaucourt A, Towers C, Josa-Cullere L, Willenbrock F, Thompson A, Hodgson D
Chemistry
. 2017 Aug;
23(65):16525-16534.
PMID: 28815753
A ring-closing alkene metathesis (RCM)/ oxyselenation-selenoxide elimination sequence was established to the sodium salts E- and Z-25 of the originally proposed structure for the recently isolated cytotoxin aruncin B (1),...
10.
Fegheh-Hassanpour Y, Arif T, Sintim H, Al Mamari H, Hodgson D
Org Lett
. 2017 Jun;
19(13):3540-3543.
PMID: 28631488
An asymmetric synthesis of (-)-6,7-dideoxysqualestatin H5 is reported. Key features of the synthesis include the following: (1) highly diastereoselective n-alkylation of a tartrate acetonide enolate and subsequent oxidation-hydrolysis to provide...