Daniel Winkelhaus
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Explore the profile of Daniel Winkelhaus including associated specialties, affiliations and a list of published articles.
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10
Citations
33
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Recent Articles
1.
Winkelhaus D, Holthausen M, Dobrovetsky R, Stephan D
Chem Sci
. 2018 Aug;
6(11):6367-6372.
PMID: 30090255
The cationic N-species [(-HCF)PN] () featuring a perfluoro-arene phosphonium group serves as a N-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N] and...
2.
LaFortune J, Johnstone T, Perez M, Winkelhaus D, Podgorny V, Stephan D
Dalton Trans
. 2016 Oct;
45(45):18156-18162.
PMID: 27785488
A family of electrophilic phenoxy-substituted phosphonium salts [(RO)P(CF)][B(CF)] (R = CH, 4-FCH, 2,4-FCH, CF) have been synthesized and their air stability was evaluated. Computations of the fluoride ion affinity and...
3.
Stein T, Perez M, Dobrovetsky R, Winkelhaus D, Caputo C, Stephan D
Angew Chem Int Ed Engl
. 2015 Jul;
54(35):10178-82.
PMID: 26178268
The combination of phosphorus(V)-based Lewis acids with diaryl amines and diaryl silylamines promotes reversible activation of dihydrogen and can be further exploited in metal-free catalytic olefin hydrogenation. Combined experimental and...
4.
Caputo C, Winkelhaus D, Dobrovetsky R, Hounjet L, Stephan D
Dalton Trans
. 2015 Mar;
44(27):12256-64.
PMID: 25785571
A series of fluorophosphonium salts, [R3PF][X] (R = alkyl or aryl; X = FB(C6F5)3, [B(C6F5)4]), have been prepared by reactions of phosphine/borane frustrated Lewis pairs (FLPs) with XeF2 or difluorophosphoranes...
5.
Winkelhaus D, Stephan D
Angew Chem Int Ed Engl
. 2014 Apr;
53(21):5414-7.
PMID: 24729472
The reaction of boron alkynes and boron azides leads to rare N3BC heterocycles resulting from aromatic C-H activation of benzene and toluene. While subsequent treatment with PMe3 gave the P-B...
6.
Winkelhaus D, Neumann B, Stammler H, Berger R, Vishnevskiy Y, Mitzel N
Chemistry
. 2012 Jun;
18(30):9312-20.
PMID: 22707351
The reaction of (C(6)F(5))(2)BH (1) with N,N-dimethylallylamine (2), N,N-diethylallylamine (3) and 1-allylpiperidine (4) afforded the five-membered ring systems (C(6)F(5))(2)B(CH(2))(3)NR(2) (R = Me (5), Et (6)) and (C(6)F(5))(2)B(CH(2))(3)N(CH(2))(5) (7) with an...
7.
Winkelhaus D, Neumann B, Stammler H, Mitzel N
Dalton Trans
. 2012 Jun;
41(30):9143-50.
PMID: 22688949
The reaction of 4-ethynyl-2,6-lutidine, (2,6-Me(2))(4-HC≡C)C(5)H(2)N (2), with B(C(6)F(5))(3) afforded the zwitterion [(2,6-Me(2))(4-(C(6)F(5))(3)BC≡C)C(5)H(2)NH] (3) via a deprotonation pathway. By treatment of 2 with the group 13 trialkyls AlMe(3), AlEt(3), GaMe(3), GaEt(3)...
8.
Winkelhaus D, Neumann B, Stammler H, Mitzel N
Dalton Trans
. 2012 Jun;
41(28):8609-14.
PMID: 22674228
The reaction of the Grignard reagent (p-C(6)F(4)H)MgBr with Me(2)SnCl(2) afforded the p-C(6)F(4)H transfer reagent Me(2)Sn(p-C(6)F(4)H)(2) (1). Subsequent reaction of 1 with BCl(3) led to the chloroborane (p-C(6)F(4)H)(2)BCl (2), which was...
9.
Caputo C, Geier S, Winkelhaus D, Mitzel N, Vukotic V, Loeb S, et al.
Dalton Trans
. 2011 Dec;
41(7):2131-9.
PMID: 22186932
The lutidine derivative (2,6-Me(2))(4-Bpin)C(5)H(2)N when combined with B(C(6)F(5))(3) yields a frustrated Lewis pair (FLP) which reacts with H(2) to give the salt [(2,6-Me(2))(4-Bpin)C(5)H(2)NH][HB(C(6)F(5))(3)] (1). Similarly 2,2'-(C(5)H(2)(4,6-Me(2))N)(2) and (4,4'-(C(5)H(2)(4,6-Me(2))N)(2) were also...
10.
Chemically fixed p-n heterojunctions for polymer electronics by means of covalent B-F bond formation
Hoven C, Wang H, Elbing M, Garner L, Winkelhaus D, Bazan G
Nat Mater
. 2010 Feb;
9(3):249-52.
PMID: 20118946
Widely used solid-state devices fabricated with inorganic semiconductors, including light-emitting diodes and solar cells, derive much of their function from the p-n junction. Such junctions lead to diode characteristics and...