Douglas W Stephan
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Explore the profile of Douglas W Stephan including associated specialties, affiliations and a list of published articles.
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Recent Articles
1.
Bedi V, Ocampochua A, Qu Z, Grimme S, Stephan D, Stephan D
Angew Chem Int Ed Engl
. 2025 Mar;
:e202503331.
PMID: 40067746
Although the nature of bis-phosphazine species are of much interest, there are few reports of their reactivity. Herein, we show that the bis-phosphazine species Ph3PNNPPh31 react with Lewis acids to...
2.
Miao L, Yeung J, Yeganeh-Salman A, Qu Z, Grimme S, Stephan D
J Am Chem Soc
. 2025 Jan;
147(6):4720-4725.
PMID: 39885726
The known species (PhP)N was previously described as two phosphine donors associated with a doubly Lewis acidic N-unit based on its thermal liberation of N. Herein, we prepare the related...
3.
Miao L, Yeganeh-Salman A, Yeung J, Stephan D
Dalton Trans
. 2024 Nov;
54(1):368-375.
PMID: 39545856
Phosphazenium cations were first characterized 60 years ago and yet little is known of their reactivity. The bidentate phosphonium dicationic salts [(CH)(PPhF)][B(CF)]2 and [(CH)(PPhCl)][Cl]3 were prepared. Reaction of 2 with...
4.
Yeung J, Yeganeh-Salman A, Miao L, Stephan D
Dalton Trans
. 2024 Nov;
53(46):18727-18735.
PMID: 39494745
The reactions of 1,1- and 1,2-bis-boranes, PhCHCH(B(CF))1 and MeSiCH(B(CF))CHB(CF)2, with -phenylenediamine and hydrazine are reported. The coordination of -phenylenediamine gives the expected adducts, PhCHCH(B(CF)(HN))CH4 and MeSiCH(B(CF))CHB(CF)((HN)CH) 6. Under thermal duress,...
5.
Tang B, Ju S, Yan W, Chen T, Stephan D, Wu Y
Chem Commun (Camb)
. 2024 Oct;
60(88):12932-12935.
PMID: 39421958
The species PhPNNC 1 reacts with the group 13 Lewis acids E(CF) (E = B or Al), HB(CF), ClAl(CF) and ECl (E = Ga or In) to give the Lewis...
6.
Major C, Lough A, Stephan D
Dalton Trans
. 2024 Jul;
53(29):12390.
PMID: 38979685
Correction for 'A chelated borinium cation' by Christopher Major , , 2024, , 10075-10078, https://doi.org/10.1039/D4DT01242A.
7.
Major C, Lough A, Stephan D
Dalton Trans
. 2024 Jun;
53(24):10075-10078.
PMID: 38855936
Two coordinate boron cations are rare. Herein we report the synthesis of [RNSiMeCH]BF (R = Dipp 3, 1-Ad 5) (Dipp = CH(iPr), Ad = CH) the reaction of BF with...
8.
Kim H, Mandal D, Ng J, Qu Z, Grimme S, Stephan D
Chemistry
. 2024 May;
30(43):e202401776.
PMID: 38735846
B(CF) and the corresponding anion [B(CF)] are ubiquitous in main group and transition metal chemistry. Known derivatives are generally limited to the incorporation of electron donating substituents. Herein we describe...
9.
Wang T, Guo Z, English L, Stephan D, Jupp A, Xu M
Angew Chem Int Ed Engl
. 2024 Mar;
63(20):e202402728.
PMID: 38483891
Cyanoketene is a fundamental molecule that is actively being searched for in the interstellar medium. Its deprotonated form (cyanoketenate) is a heterocumulene that is isoelectronic to carbon suboxide whose structure...
10.
Thomson J, Michailovich S, Miao L, Farrell J, Murray J, Lough A, et al.
Dalton Trans
. 2024 Mar;
53(13):5775-5778.
PMID: 38465721
-Substitution reactions on CF rings of Lewis acids have been exploited to achieve triply substituted derivatives. The reaction of B(CF) with P(SiMe) ultimately affords the Lewis acid B(CFP(SiMe))1. This species...