Daniel T Gryko
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Explore the profile of Daniel T Gryko including associated specialties, affiliations and a list of published articles.
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209
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1170
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Recent Articles
1.
Skonieczny K, Di Maiolo F, Venturi S, Iagatti A, Ricci A, Bertocchi F, et al.
Phys Chem Chem Phys
. 2025 Feb;
PMID: 40017439
Two complex π-expanded diketopyrrolopyrroles (EDPPs) have been prepared following a multistep but straightforward strategy. We discovered that the fate of these molecules in the excited state can be controlled by...
2.
Gorski K, Shelton S, Lingagouder J, Data P, Jacquemin D, Gryko D
Chem Sci
. 2025 Feb;
PMID: 39991555
The present work is focused on designing novel heteroaromatic systems, formally a hybrid of dibenzo[,]oxazepines and 1,4-dihydropyrrolo[3,2-]pyrroles (DHPPs). Straightforward synthesis affords a family of rigid, centrosymmetric, π-expanded aromatic heterocycles amenable...
3.
Kusy D, Gorski K, Bertocchi F, Galli M, Vanthuyne N, Terenziani F, et al.
Chemistry
. 2025 Jan;
31(12):e202404632.
PMID: 39838917
Herein, we report the synthesis and chiroptical characteristics of the first (double) helicenes possessing the 1,4-dihydropyrrolo[3,2-b]pyrrole (DHPP) moiety as their central core. We have developed a three-step synthesis with 6π-electrocyclization...
4.
Sanil G, Dobrzycki L, Cyranski M, Jacquemin D, Chaladaj W, Gryko D
J Org Chem
. 2024 Dec;
90(1):614-622.
PMID: 39741379
Drastic changes to the character of the acidic catalyst enable the reversal of the double alkyne benzannulation reaction output. In the presence of a strong Brønsted acid, 1,4-dihydropyrrolopyrroles undergo transformation...
5.
Szymanski B, Sahoo S, Vakuliuk O, Valiev R, Ramazanov R, Laski P, et al.
Chem Sci
. 2024 Dec;
16(5):2170-2179.
PMID: 39664808
In this work, we disclose a series of seven quadrupolar centrosymmetric 1,4-dihydropyrrolo[3,2-]pyrroles (DHPPs) linked to the two peripheral, strongly electron-accepting heterocycles such as benzoxadiazole, benzothiadiazole and benzoselenadiazole. This represents the...
6.
Roszak R, Gadina L, Wolos A, Makkawi A, Mikulak-Klucznik B, Bilgi Y, et al.
Nat Commun
. 2024 Nov;
15(1):10285.
PMID: 39604395
Discovery of new types of reactions is essential to organic chemistry because it expands the scope of accessible molecular scaffolds and can enable more economical syntheses of existing structures. In...
7.
Gorski K, Pejov L, Jorgensen K, Knysh I, Jacquemin D, Gryko D
Chemistry
. 2024 Nov;
31(9):e202404094.
PMID: 39587457
Here we present a highly versatile synthetic strategy based on twofold 6π-electrocyclization accompanied with HBr elimination as a novel approach towards centrosymmetric multi-heteroatom-doped nanographenes build around an electron-rich 1,4-dihydropyrrolo[3,2-b]pyrrole core....
8.
Erdemir G, Knysh I, Skonieczny K, Jacquemin D, Gryko D
J Org Chem
. 2024 Oct;
89(21):15513-15522.
PMID: 39444365
The outcome of the reaction of tetracyanoethylene with 1,4-dihydropyrrolo[3,2-]pyrroles (DHPPs) strongly depends on the character of the substituents present at positions 2 and 5. With electron-withdrawing substituents, the reaction does...
9.
Magnasco L, Lanfranchi A, Martusciello M, Megahd H, Manfredi G, Lova P, et al.
ACS Omega
. 2024 Oct;
9(41):42375-42385.
PMID: 39431069
The increasing prevalence and detrimental effects of volatile organic compounds are driving the need for selective on-site sensors that do not require complex sampling or instrumentation. Broadband selective sensors exhibiting...
10.
Govind C, Balanikas E, Sanil G, Gryko D, Vauthey E
Chem Sci
. 2024 Oct;
PMID: 39371465
Whereas the photoinduced charge-transfer properties of electron donor-acceptor dyads are now well understood, those of symmetric conjugated architectures containing several identical donor-acceptor branches have started to be scrutinised much more...