Christopher A Russell
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Explore the profile of Christopher A Russell including associated specialties, affiliations and a list of published articles.
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61
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455
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Recent Articles
1.
Scott S, Cadge J, Boden G, Bower J, Russell C
Angew Chem Int Ed Engl
. 2023 Mar;
62(23):e202301526.
PMID: 36995930
We describe a Au complex of a hemi-labile (C^N) N-heterocyclic carbene ligand that is able to mediate oxidative addition of aryl iodides. Detailed computational and experimental investigations have been undertaken...
2.
Cadge J, Gates P, Bower J, Russell C
J Am Chem Soc
. 2022 Oct;
144(43):19719-19725.
PMID: 36282061
A MeDalPhos-ligated gold(III) metallafluorene complex, generated via C-C oxidative addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and computational studies show that this proceeds via a hitherto unknown...
3.
Cadge J, Bower J, Russell C
Angew Chem Int Ed Engl
. 2021 Sep;
60(47):24976-24983.
PMID: 34533267
A combined theoretical and experimental approach has been used to study the unusual mechanism of oxidative addition of aryl iodides to [bipyAu(C H )] complexes. The modular nature of this...
4.
Cadge J, Sparkes H, Bower J, Russell C
Angew Chem Int Ed Engl
. 2020 Jan;
59(16):6617-6621.
PMID: 31951062
The first isolated examples of intermolecular oxidative addition of alkenyl and alkynyl iodides to Au are reported. Using a 5,5'-difluoro-2,2'-bipyridyl ligated complex, oxidative addition of geometrically defined alkenyl iodides occurs...
5.
Falconer R, Zeng D, Green M, Stephan D, McGrady J, Russell C
Chemistry
. 2019 Aug;
25(54):12507-12511.
PMID: 31414704
The aromatic heterocycle 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene reacts with a series of silanes, germanes and stannanes, with weaker E-H bonds reacting in an increasingly facile manner. All react by 1,4-addition to give bicyclic...
6.
Harper M, Arthur C, Crosby J, Emmett E, Falconer R, Fensham-Smith A, et al.
J Am Chem Soc
. 2018 Mar;
140(12):4440-4445.
PMID: 29553258
Three-coordinate bipyridyl complexes of gold, [(κ-bipy)Au(η-CH)][NTf], are readily accessed by direct reaction of 2,2'-bipyridine (bipy), or its derivatives, with the homoleptic gold ethylene complex [Au(CH)][NTf]. The cheap and readily available...
7.
Liu L, Zhou J, Cao L, Andrews R, Falconer R, Russell C, et al.
J Am Chem Soc
. 2017 Dec;
140(1):147-150.
PMID: 29272583
A room-temperature-stable crystalline 2H-phosphirene (1) was prepared by treatment of an electrophilic diamidocarbene with tert-butylphosphaalkyne. Compound 1 is shown to react as a vinylphosphinidene generated via phosphirene-phosphinidene rearrangement. Thermolysis is...
8.
Harper M, Emmett E, Bower J, Russell C
J Am Chem Soc
. 2017 Aug;
139(36):12386-12389.
PMID: 28829593
Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic...
9.
Haller L, Mas-Marza E, Cybulski M, Sanguramath R, Macgregor S, Mahon M, et al.
Dalton Trans
. 2017 Mar;
46(9):2861-2873.
PMID: 28245022
Relativistic density functional theory calculations, both with and without the effects of spin-orbit coupling, have been employed to model hydride NMR chemical shifts for a series of [Ru(NHC)(L)H] species (NHC...
10.
Corrie T, Ball L, Russell C, Lloyd-Jones G
J Am Chem Soc
. 2016 Dec;
139(1):245-254.
PMID: 27936749
The intramolecular gold-catalyzed arylation of arenes by aryl-trimethylsilanes has been investigated from both mechanistic and preparative aspects. The reaction generates 5- to 9-membered rings, and of the 44 examples studied,...