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Carlos M Cruz

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Articles 26
Citations 206
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Recent Articles
1.
Palomo L, Cruz C, Campana A, Jiang B, Wu J, Casado J, et al.
ACS Omega . 2025 Mar; 10(7):6419-6426. PMID: 40028058
Chiral macrocycles are an attractive subject in supramolecular chemistry because of their proven relevance in appealing applications such as asymmetric catalysis, selective absorption, or chiral recognition. Taking into account the...
2.
Ye Y, Poncet M, Yaltseva P, Salcedo-Abraira P, Rodriguez-Dieguez A, Martin J, et al.
Chem Sci . 2025 Feb; PMID: 39991562
Three homoleptic spin-flip (SF) emitters, namely [Cr(Mebipzp)] (1), [Cr(IMebipzp)] (2) and [Cr(bip*)] (3), have been successfully synthesized and characterized. The weak distortion compared to a perfect octahedron imparts favourable structural...
3.
Jaafar A, Guerra-Gonzalez D, Pascual A, Ortuno A, Cruz C, Cuerva J, et al.
RSC Med Chem . 2025 Feb; PMID: 39925736
Despite significant progress in drug discovery, there remains an urgent need to identify new structures capable of targeting drug-resistant diseases, as well as novel pathogens, to address the growing challenges...
4.
Kovida K, Malincik J, Cruz C, Campana A, Solomek T
Chem Sci . 2024 Dec; 16(3):1405-1410. PMID: 39713755
Development of chiral organic materials with a strong chiroptical response is crucial to advance technologies based on circularly polarized luminescence, enantioselective sensing, or unique optical signatures in anti-counterfeiting. The progress...
5.
Gomez A, David A, Campana A, Cuerva J, Diaz-Casado L, Uriel C, et al.
J Org Chem . 2024 Dec; 89(24):18522-18528. PMID: 39654055
Herein, we report the synthesis of novel dimeric urea-bridged BODIPY-carbohydrate conjugates, which display circularly polarized luminescence (CPL). The dimers are composed of diastereomerically pure, axially chiral (P or M) BODIPY...
6.
Ye Y, Cruz C, Doistau B, Colacio E, Piguet C, Herrera J, et al.
Inorg Chem . 2024 Nov; 63(50):23886-23893. PMID: 39609096
The thermodynamically controlled self-assembly of bis-bidentate quaterpyridine ligand, L = 2,2':5',5″:2″,2‴-quaterpyridine, with Cr and subsequent oxidation to Cr yields the first photoluminescent tetrahedral [CrL] molecular cage. Single-crystal X-ray diffraction reveals...
7.
Uceda R, Gijon A, Miguez-Lago S, Cruz C, Blanco V, Fernandez-Alvarez F, et al.
Angew Chem Int Ed Engl . 2024 Sep; 63(49):e202409998. PMID: 39329214
The relationship between chemical structure and chiroptical properties is not always clearly understood. Nowadays, efforts to develop new systems with enhanced optical properties follow the trial-error method. A large number...
8.
Chong J, Benchohra A, Besnard C, Guenee L, Rosspeintner A, Cruz C, et al.
Dalton Trans . 2024 Jul; 53(38):15801-15814. PMID: 39011611
Complete or partial replacement of well-known five-membered chelating 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) ligands with analogous didentate 2,2'-biimidazole (Hbiim) provides novel perspectives for exploiting the latter pH-tuneable bridging unit for...
9.
Martinez-Pinel A, Lezama L, Cuerva J, Casares R, Blanco V, Cruz C, et al.
Org Lett . 2024 Jul; 26(28):6012-6017. PMID: 38967257
We report the synthesis and study of the optoelectronic, magnetic, and chiroptical properties of a helically chiral diradicaloid based on dibenzoindeno[2,1-]fluorene. The molecule shows a small HOMO-LUMO gap and a...
10.
Pazos A, Cruz C, Cuerva J, Rivilla I, Cossio F, Freixa Z
Angew Chem Int Ed Engl . 2024 Apr; 63(26):e202406663. PMID: 38655628
A pair of enantiopure [6]-azairidahelicenes incorporating chirality at the metal center and on the helicenic ligand were synthesized by dynamic kinetic resolution (dkr) of a configurationally labile [4]-helicenic ligand (4-(2-pyridyl)-benzo[g]phenanthrene,...