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Berwyck L J Poad

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Articles 61
Citations 584
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Recent Articles
1.
Shiels O, Brydon S, Poad B, Marshall D, Houston S, Xing H, et al.
Chem Sci . 2025 Jan; 16(6):2861-2878. PMID: 39822901
Although electrostatic catalysis can enhance the kinetics and selectivity of reactions to produce greener synthetic processes, the highly directional nature of electrostatic interactions has limited widespread application. In this study,...
2.
Kelly P, Turner J, Shiels O, da Silva G, Blanksby S, Poad B, et al.
Phys Chem Chem Phys . 2024 Dec; 27(1):83-95. PMID: 39652099
In combustion, acetylene is a key species in molecular-weight growth reactions that form polycyclic aromatic hydrocarbons (PAHs) and ultimately soot particles. Radical addition to acetylene generates a vinyl radical intermediate,...
3.
Lloyd Williams O, Cox C, Zhang M, Lessio M, Rusli O, Donald W, et al.
Dalton Trans . 2024 Oct; 53(46):18473-18483. PMID: 39352246
Here the monocation complexes of seven -cryptophanes are examined with high-resolution ion-mobility mass spectrometry. The relative size of the [cation + cryptophane] complexes were compared based on their measured mobilities...
4.
Shvartsburg A, Sadowski P, Poad B, Blanksby S
Anal Chem . 2024 Sep; 96(40):15960-15969. PMID: 39334534
Specific lipid isomers are functionally critical, but their structural rigidity and usually minute geometry differences make separating them harder than other biomolecules. Such separations by ion mobility spectrometry (IMS) were...
5.
Do P, Sbordone F, Kalmer H, Sokolova A, Zhang C, Thai L, et al.
Chem Sci . 2024 Aug; 15(31):12410-12419. PMID: 39118612
The advent of reversible deactivation radical polymerization (RDRP) revolutionized polymer chemistry and paved the way for accessing synthetic polymers with controlled sequences based on vinylic monomers. An inherent limitation of...
6.
Brydon S, Poad B, Fang M, Rustam Y, Young R, Mouradov D, et al.
J Am Soc Mass Spectrom . 2024 Jul; 35(8):1976-1990. PMID: 39037040
The onset and progression of cancer is associated with changes in the composition of the lipidome. Therefore, better understanding of the molecular mechanisms of these disease states requires detailed structural...
7.
Shiels O, Marlton S, Poad B, Blanksby S, da Silva G, Trevitt A
J Phys Chem A . 2024 Jan; 128(2):413-419. PMID: 38174881
In the gas-phase chemistry of the atmosphere and automotive fuel combustion, peroxyl radical intermediates are formed following O addition to carbon-centered radicals which then initiate a complex network of radical...
8.
Michael J, Young R, Balez R, Jekimovs L, Marshall D, Poad B, et al.
Angew Chem Int Ed Engl . 2024 Jan; 63(9):e202316793. PMID: 38165069
In recent years there has been a significant interest in the development of innovative lipidomics techniques capable of resolving lipid isomers. To date, methods applied to resolving sn-isomers have resolved...
9.
Poad B, Jekimovs L, Young R, Wongsomboon P, Marshall D, Hansen F, et al.
Anal Chem . 2023 Oct; 95(43):15917-15923. PMID: 37847864
Many families of lipid isomers remain unresolved by contemporary liquid chromatography-mass spectrometry approaches, leading to a significant underestimation of the structural diversity within the lipidome. While ion mobility coupled to...
10.
Claes B, Bowman A, Poad B, Heeren R, Blanksby S, Ellis S
J Am Soc Mass Spectrom . 2023 Aug; 34(10):2269-2277. PMID: 37581874
The biological functions of lipids are entirely dependent on their molecular structures with even small changes in structure─such as different sites of unsaturation─providing critical markers for changes in the underlying...