The Role of Water in Carbon Dioxide Adsorption in Porphyrinic Metal-Organic Frameworks

Overview

Journal ChemCatChem

Date 2024 Mar 20

PMID 38505862

Authors

Bettina Baumgartner

P Tim Prins

Jaap N Louwen

Matteo Monai

Bert M Weckhuysen

Affiliations

Soon will be listed here.

Abstract

Capturing and converting CO through artificial photosynthesis using photoactive, porous materials is a promising approach for addressing increasing CO concentrations. Porphyrinic Zr-based metal-organic frameworks (MOFs) are of particular interest as they incorporate a photosensitizer in the porous structure. Herein, the initial step of the artificial photosynthesis is studied: CO sorption and activation in the presence of water. A combined vibrational and visible spectroscopic approach was used to monitor the adsorption of CO into PCN-222 and PCN-223 MOFs, and the photophysical changes of the porphyrinic linker as a function of water concentration. A shift in CO sorption site and bending of the porphyrin macrocycle in response to humidity was observed, and CO/HO competition experiments revealed that the exchange of CO with HO is pore-size dependent. Therefore, humidity and pore-size can be used to tune CO sorption, CO capacity, and light harvesting in porphyrinic MOFs, which are key factors for CO photoreduction.

Citing Articles

Adsorption in Pyrene-Based Metal-Organic Frameworks: The Role of Pore Structure and Topology.

Pougin M, P Domingues N, Uran F, Ortega-Guerrero A, Ireland C, Espin J ACS Appl Mater Interfaces. 2024; 16(28):36586-36598.

PMID: 38978297 PMC: 11261566. DOI: 10.1021/acsami.4c05527.

The Role of Water in Carbon Dioxide Adsorption in Porphyrinic Metal-Organic Frameworks.

Baumgartner B, Prins P, Louwen J, Monai M, Weckhuysen B ChemCatChem. 2024; 15(19):e202300722.

PMID: 38505862 PMC: 10946852. DOI: 10.1002/cctc.202300722.

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Baumgartner B, Prins P, Louwen J, Monai M, Weckhuysen B . The Role of Water in Carbon Dioxide Adsorption in Porphyrinic Metal-Organic Frameworks. ChemCatChem. 2024; 15(19):e202300722. PMC: 10946852. DOI: 10.1002/cctc.202300722. View