Lattice Adaptivity Triggered by Solid-gas Reactions of Cationic Group 7 Pincer Complexes

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2023 Aug 21

PMID 37602809

Authors

Joe C Goodall

M Arif Sajjad

Emily A Thompson

Samuel J Page

Adam M Kerrigan

Huw T Jenkins

Jason M Lynam

Stuart A Macgregor

Andrew S Weller

Affiliations

Soon will be listed here.

Abstract

The group 7 complexes [M(κ-2,6-(RPO)CHN)(CO)L][BAr] [M = Mn, R = Pr, L = THF; M = Re, R = Bu, L = vacant site] undergo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

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