Modulated Self-assembly of Three Flexible Cr(III) PCPs for SO Adsorption and Detection

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2023 Jun 12

PMID 37306073

Authors

Valeria B Lopez-Cervantes

Dominic Bara

Ana Yanez-Aulestia

Eva Martinez-Ahumada

Alfredo Lopez-Olvera

Yoarhy A Amador-Sanchez

Diego Solis-Ibarra

Eli Sanchez-Gonzalez

Ilich A Ibarra

Ross S Forgan

Affiliations

Soon will be listed here.

Abstract

Modulated self-assembly protocols are used to develop facile, HF-free syntheses of the archetypal flexible PCP, MIL-53(Cr), and novel isoreticular analogues MIL-53(Cr)-Br and MIL-53(Cr)-NO. All three PCPs show good SO uptake (298 K, 1 bar) and high chemical stabilities against dry and wet SO. Solid-state photoluminescence spectroscopy indicates all three PCPs exhibit turn-off sensing of SO, in particular MIL-53(Cr)-Br, which shows a 2.7-fold decrease in emission on exposure to SO at room temperature, indicating potential sensing applications.

Citing Articles

Achieving Sub-ppm Sensitivity in SO Detection with a Chemically Stable Covalent Organic Framework.

Zhao W, Obeso J, Lopez-Cervantes V, Bahri M, Sanchez-Gonzalez E, Amador-Sanchez Y Angew Chem Int Ed Engl. 2024; 64(3):e202415088.

PMID: 39297429 PMC: 11735898. DOI: 10.1002/anie.202415088.

References

Bourrelly S, Moulin B, Rivera A, Maurin G, Devautour-Vinot S, Serre C . Explanation of the adsorption of polar vapors in the highly flexible metal organic framework MIL-53(Cr). J Am Chem Soc. 2010; 132(27):9488-98. DOI: 10.1021/ja1023282. View

Rahman S, Arami-Niya A, Yang X, Xiao G, Li G, May E . Temperature dependence of adsorption hysteresis in flexible metal organic frameworks. Commun Chem. 2023; 3(1):186. PMC: 9814463. DOI: 10.1038/s42004-020-00429-3. View

Schneemann A, Bon V, Schwedler I, Senkovska I, Kaskel S, Fischer R . Flexible metal-organic frameworks. Chem Soc Rev. 2014; 43(16):6062-96. DOI: 10.1039/c4cs00101j. View

Wu L, Chaplais G, Xue M, Qiu S, Patarin J, Simon-Masseron A . New functionalized MIL-53(In) solids: syntheses, characterization, sorption, and structural flexibility. RSC Adv. 2022; 9(4):1918-1928. PMC: 9059721. DOI: 10.1039/c8ra08522f. View

Osterrieth J, Rampersad J, Madden D, Rampal N, Skoric L, Connolly B . How Reproducible are Surface Areas Calculated from the BET Equation?. Adv Mater. 2022; 34(27):e2201502. DOI: 10.1002/adma.202201502. View

Krause S, Hosono N, Kitagawa S . Chemistry of Soft Porous Crystals: Structural Dynamics and Gas Adsorption Properties. Angew Chem Int Ed Engl. 2020; 59(36):15325-15341. DOI: 10.1002/anie.202004535. View

Lin R, Liu S, Ye J, Li X, Zhang J . Photoluminescent Metal-Organic Frameworks for Gas Sensing. Adv Sci (Weinh). 2016; 3(7):1500434. PMC: 5069648. DOI: 10.1002/advs.201500434. View

Bara D, Meekel E, Pakamore I, Wilson C, Ling S, Forgan R . Exploring and expanding the Fe-terephthalate metal-organic framework phase space by coordination and oxidation modulation. Mater Horiz. 2021; 8(12):3377-3386. PMC: 8628537. DOI: 10.1039/d1mh01663f. View

Munn A, Pillai R, Biswas S, Stock N, Maurin G, Walton R . The flexibility of modified-linker MIL-53 materials. Dalton Trans. 2015; 45(10):4162-8. DOI: 10.1039/c5dt03438h. View

10.

Forgan R . Modulated self-assembly of metal-organic frameworks. Chem Sci. 2021; 11(18):4546-4562. PMC: 8159241. DOI: 10.1039/d0sc01356k. View

11.

Millange F, Serre C, Ferey G . Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first CrIII hybrid inorganic-organic microporous solids: CrIII(OH).(O2C-C6H4-CO2).(HO2C-C6H4-CO2H)x. Chem Commun (Camb). 2002; (8):822-3. DOI: 10.1039/b201381a. View

12.

Ghosh S, Zhang J, Kitagawa S . Reversible topochemical transformation of a soft crystal of a coordination polymer. Angew Chem Int Ed Engl. 2007; 46(42):7965-8. DOI: 10.1002/anie.200703086. View

13.

Clearfield A . Flexible MOFs under stress: pressure and temperature. Dalton Trans. 2015; 45(10):4100-12. DOI: 10.1039/c5dt03228h. View

14.

Hazra A, van Heerden D, Sanyal S, Lama P, Esterhuysen C, Barbour L . CO-induced single-crystal to single-crystal transformations of an interpenetrated flexible MOF explained by crystallographic analysis and molecular modeling. Chem Sci. 2020; 10(43):10018-10024. PMC: 6977545. DOI: 10.1039/c9sc04043a. View

15.

Li H, Zhao S, Zang S, Li J . Functional metal-organic frameworks as effective sensors of gases and volatile compounds. Chem Soc Rev. 2020; 49(17):6364-6401. DOI: 10.1039/c9cs00778d. View

16.

Lopez-Olvera A, Zarate J, Martinez-Ahumada E, Fan D, Diaz-Ramirez M, Saenz-Cavazos P . SO Capture by Two Aluminum-Based MOFs: Rigid-like MIL-53(Al)-TDC Breathing MIL-53(Al)-BDC. ACS Appl Mater Interfaces. 2021; 13(33):39363-39370. DOI: 10.1021/acsami.1c09944. View

17.

Cui X, Yang Q, Yang L, Krishna R, Zhang Z, Bao Z . Ultrahigh and Selective SO Uptake in Inorganic Anion-Pillared Hybrid Porous Materials. Adv Mater. 2017; 29(28). DOI: 10.1002/adma.201606929. View

18.

Nijem N, Wu H, Canepa P, Marti A, Balkus Jr K, Thonhauser T . Tuning the gate opening pressure of Metal-Organic Frameworks (MOFs) for the selective separation of hydrocarbons. J Am Chem Soc. 2012; 134(37):15201-4. DOI: 10.1021/ja305754f. View

19.

Iremonger S, Vaidhyanathan R, Mah R, Shimizu G . Zn7O2(RCOO)10 clusters and nitro aromatic linkers in a porous metal-organic framework. Inorg Chem. 2013; 52(8):4124-6. DOI: 10.1021/ic302127y. View

20.

Takashima Y, Martinez V, Furukawa S, Kondo M, Shimomura S, Uehara H . Molecular decoding using luminescence from an entangled porous framework. Nat Commun. 2011; 2:168. PMC: 3134948. DOI: 10.1038/ncomms1170. View