Pore "Softening" and Emergence of Breathability Effects of New Keplerate Nano-Containers

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2023 Feb 22

PMID 36812050

Authors

Alexander Elliott

James McAllister

De-Liang Long

Yu-Fei Song

Haralampos N Miras

Affiliations

Soon will be listed here.

Abstract

The self-assembly of porous molecular nanocapsules offer unique opportunities to investigate a range of interesting phenomena and applications. However, to design nanocapsules with pre-defined properties, thorough understanding of their structure-property relation is required. Here, we report the self-assembly of two elusive members of the Keplerate family, [Mo Se O (H O) (AcO) ] {Mo Se } 1 and [W Mo Se O (H O) (AcO) ] {W Mo Se } 2, that have been synthesised using pentagonal and dimeric ([Mo O Se ] ) building blocks and their structures have been confirmed via single crystal X-ray diffractions. Our comparative study involving the uptake of organic ions and the related ligand exchange of various ligand sizes by the {Mo Se } and previously reported Keplerates {Mo O }, {Mo S } based on the ligand exchange rates, revealed the emergence of increased "breathability" that dominates over the pore size as we transition from the {Mo S } to the "softer" {Mo Se } molecular nano-container.

Citing Articles

Pore "Softening" and Emergence of Breathability Effects of New Keplerate Nano-Containers.

Elliott A, McAllister J, Long D, Song Y, Miras H Angew Chem Int Ed Engl. 2023; 62(20):e202218897.

PMID: 36812050 PMC: 10946700. DOI: 10.1002/anie.202218897.

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