The Assignment of B and H Resonances in the Post-reaction Mixture from the Dry Synthesis of Li(BH NH BH NH BH )

We report a detailed NMR and NMR study of as synthesised obtained in a novel dry-synthesis method. A combination of 1D and 2D single- and triple-quantum techniques was used for the assignment of all observed signals. Minor side-products and reactants were detected in the product: , , , and two yet unknown salts containing 7-membered chain anions: and . We believe the assignment provided within this study might be helpful when analysing the mixtures containing numerous ammonia borane derivatives, which often give overlapping signals that are hard to distinguish.