Homogeneous Carbon Capture and Catalytic Hydrogenation: Toward a Chemical Hydrogen Battery System

Overview

Journal JACS Au

Publisher American Chemical Society

Specialty Chemistry

Date 2022 Jun 1

PMID 35647600

Authors

Duo Wei

Rui Sang

Ayeshe Moazezbarabadi

Henrik Junge

Matthias Beller

Affiliations

Soon will be listed here.

Abstract

Recent developments of CO capture and subsequent catalytic hydrogenation to C1 products are discussed and evaluated in this Perspective. Such processes can become a crucial part of a more sustainable energy economy in the future. The individual steps of this catalytic carbon capture and usage (CCU) approach also provide the basis for chemical hydrogen batteries. Here, specifically the reversible CO/formic acid (or bicarbonate/formate salts) system is presented, and the utilized catalysts are discussed.

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References

Jakobsen J, Ronne M, Daasbjerg K, Skrydstrup T . Are Amines the Holy Grail for Facilitating CO Reduction?. Angew Chem Int Ed Engl. 2021; 60(17):9174-9179. DOI: 10.1002/anie.202014255. View

Huff C, Sanford M . Cascade catalysis for the homogeneous hydrogenation of CO2 to methanol. J Am Chem Soc. 2011; 133(45):18122-5. DOI: 10.1021/ja208760j. View

Rezayee N, Huff C, Sanford M . Tandem amine and ruthenium-catalyzed hydrogenation of CO2 to methanol. J Am Chem Soc. 2015; 137(3):1028-31. DOI: 10.1021/ja511329m. View

Mellmann D, Sponholz P, Junge H, Beller M . Formic acid as a hydrogen storage material - development of homogeneous catalysts for selective hydrogen release. Chem Soc Rev. 2016; 45(14):3954-88. DOI: 10.1039/c5cs00618j. View

Fellay C, Dyson P, Laurenczy G . A viable hydrogen-storage system based on selective formic acid decomposition with a ruthenium catalyst. Angew Chem Int Ed Engl. 2008; 47(21):3966-8. DOI: 10.1002/anie.200800320. View

Tanaka R, Yamashita M, Nozaki K . Catalytic hydrogenation of carbon dioxide using Ir(III)-pincer complexes. J Am Chem Soc. 2009; 131(40):14168-9. DOI: 10.1021/ja903574e. View

Kothandaraman J, Kar S, Sen R, Goeppert A, Olah G, Prakash G . Efficient Reversible Hydrogen Carrier System Based on Amine Reforming of Methanol. J Am Chem Soc. 2017; 139(7):2549-2552. DOI: 10.1021/jacs.6b11637. View

Wang W, Wang S, Ma X, Gong J . Recent advances in catalytic hydrogenation of carbon dioxide. Chem Soc Rev. 2011; 40(7):3703-27. DOI: 10.1039/c1cs15008a. View

Chatterjee S, Huang K . Unrealistic energy and materials requirement for direct air capture in deep mitigation pathways. Nat Commun. 2020; 11(1):3287. PMC: 7335053. DOI: 10.1038/s41467-020-17203-7. View

10.

Wang W, Himeda Y, Muckerman J, Manbeck G, Fujita E . CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction. Chem Rev. 2015; 115(23):12936-73. DOI: 10.1021/acs.chemrev.5b00197. View

11.

Kothandaraman J, Czaun M, Goeppert A, Haiges R, Jones J, May R . Amine-free reversible hydrogen storage in formate salts catalyzed by ruthenium pincer complex without pH control or solvent change. ChemSusChem. 2015; 8(8):1442-51. DOI: 10.1002/cssc.201403458. View

12.

Papp G, Csorba J, Laurenczy G, Joo F . A charge/discharge device for chemical hydrogen storage and generation. Angew Chem Int Ed Engl. 2011; 50(44):10433-5. DOI: 10.1002/anie.201104951. View

13.

Kothandaraman J, Heldebrant D . Catalytic coproduction of methanol and glycol in one pot from epoxide, CO, and H. RSC Adv. 2022; 10(69):42557-42563. PMC: 9057970. DOI: 10.1039/d0ra09459e. View

14.

Kar S, Goeppert A, Prakash G . Integrated CO Capture and Conversion to Formate and Methanol: Connecting Two Threads. Acc Chem Res. 2019; 52(10):2892-2903. DOI: 10.1021/acs.accounts.9b00324. View

15.

Hull J, Himeda Y, Wang W, Hashiguchi B, Periana R, Szalda D . Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures. Nat Chem. 2012; 4(5):383-8. DOI: 10.1038/nchem.1295. View

16.

Elsby M, Baker R . Strategies and mechanisms of metal-ligand cooperativity in first-row transition metal complex catalysts. Chem Soc Rev. 2020; 49(24):8933-8987. DOI: 10.1039/d0cs00509f. View

17.

Yang H, Xu Z, Fan M, Gupta R, Slimane R, Bland A . Progress in carbon dioxide separation and capture: a review. J Environ Sci (China). 2008; 20(1):14-27. DOI: 10.1016/s1001-0742(08)60002-9. View

18.

Shao Z, Li Y, Liu C, Ai W, Luo S, Liu Q . Reversible interconversion between methanol-diamine and diamide for hydrogen storage based on manganese catalyzed (de)hydrogenation. Nat Commun. 2020; 11(1):591. PMC: 6992753. DOI: 10.1038/s41467-020-14380-3. View

19.

Liu A, Ma R, Song C, Yang Z, Yu A, Cai Y . Equimolar CO2 capture by N-substituted amino acid salts and subsequent conversion. Angew Chem Int Ed Engl. 2012; 51(45):11306-10. DOI: 10.1002/anie.201205362. View

20.

Schwander T, Schada von Borzyskowski L, Burgener S, Cortina N, Erb T . A synthetic pathway for the fixation of carbon dioxide in vitro. Science. 2016; 354(6314):900-904. PMC: 5892708. DOI: 10.1126/science.aah5237. View