Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-pincer Complexes

Overview

Journal J Am Chem Soc

Publisher American Chemical Society

Specialty Chemistry

Date 2009 Sep 25

PMID 19775157

Citations 57

Authors

Ryo Tanaka

Makoto Yamashita

Kyoko Nozaki

Affiliations

Soon will be listed here.

Abstract

Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3,500,000 and a turnover frequency of 150,000 h(-1), both of which are the highest values reported to date.

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