Mechanocatalytic Polymerization and Cross-Linking in a Polymeric Matrix

A latent olefin metathesis catalyst, bearing two polymeric NHC ligands, was embedded in a semicrystalline polymer matrix containing cyclic olefins. The catalyst was activated by straining the solid material under compression, resulting in polymerization and cross-linking reactions of the monomers in situ. Catalyst activation in the solid state may be employed in new self-healing materials.