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Synthesis of Discrete Catalytic Oligomers and Their Potential in Silica-supported Cooperative Catalysis

Overview
Journal RSC Adv
Specialty Chemistry
Date 2022 May 6
PMID 35519338
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Abstract

Cooperative catalysis on solid surfaces relies primarily on two or more catalytic partners being close enough to each other to sustain the catalytic cycle. We describe here the synthesis and preliminary investigation of discrete homo-oligomers as flexible scaffolds to inflect the intersite distance and blur the compositional heterogeneity in a silica-grafted catalytic triad.

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References
1.
Margelefsky E, Bendjeriou A, Zeidan R, Dufaud V, Davis M . Nanoscale organization of thiol and arylsulfonic acid on silica leads to a highly active and selective bifunctional, heterogeneous catalyst. J Am Chem Soc. 2008; 130(40):13442-9. DOI: 10.1021/ja804082m. View

2.
Rabeah J, Bentrup U, Stosser R, Bruckner A . Selective Alcohol Oxidation by a Copper TEMPO Catalyst: Mechanistic Insights by Simultaneously Coupled Operando EPR/UV-Vis/ATR-IR Spectroscopy. Angew Chem Int Ed Engl. 2015; 54(40):11791-4. DOI: 10.1002/anie.201504813. View

3.
Yu C, He J . Synergic catalytic effects in confined spaces. Chem Commun (Camb). 2012; 48(41):4933-40. DOI: 10.1039/c2cc31585h. View

4.
Notestein J, Katz A . Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces. Chemistry. 2006; 12(15):3954-65. DOI: 10.1002/chem.200501152. View

5.
Barnes J, Ehrlich D, Gao A, Leibfarth F, Jiang Y, Zhou E . Iterative exponential growth of stereo- and sequence-controlled polymers. Nat Chem. 2015; 7(10):810-5. DOI: 10.1038/nchem.2346. View