Anodic Stripping Voltammetry on a Carbon-based Ion-Selective Electrode

Overview

Journal Electrochim Acta

Date 2021 Sep 6

PMID 34483347

Citations 10

Authors

Suji Park

Claudia S Maier

Dipankar Koley

Affiliations

Soon will be listed here.

Abstract

In this study, we demonstrated the unique capability of carbon-based ion-selective electrode (ISE) to perform highly sensitive square wave anodic stripping voltammetry, while maintaining all the properties of an ISE, in terms of sensitivity, detection limit, response time and selectivity. Square wave anodic stripping voltammetry involves deposition and dissolution steps of metal ions, which means adsorption and desorption of metal ions on the conductive ion-selective membrane without losing its ion-sensing property. To demonstrate this capability, we chose a Ca ion-selective microelectrode (μISE) as a potentiometric method and Cu-stripping voltammetry as an amperometric method. The carbon-based ISE surface is capable of quantifying nanomolar to micromolar Cu in both a standard acetate buffer and a complex water sample. The Ca-μISE also showed a Nernstian slope of 29 mV / log [Ca] and a detection limit of 1 μM within the linear range of 1 μM to 10 mM. It thus opens an opportunity to use the low detection limit of anodic stripping voltammetry and the high selectivity of ISE-based potentiometry.

Citing Articles

Triple-function carbon-based Ca ion-selective pH ring microelectrode to study real-time bacteria-mediated hydroxyapatite corrosion.

Sheet P, Park S, Nguyen A, George S, Maier C, Koley D Anal Chim Acta. 2024; 1321:343042.

PMID: 39155097 PMC: 11540006. DOI: 10.1016/j.aca.2024.343042.

Laser-induced graphene electrochemical sensor for quantitative detection of phytotoxic aluminum ions (Al) in soils extracts.

Reyes-Loaiza V, De La Roche J, Hernandez-Renjifo E, Idarraga O, da Silva M, Valencia D Sci Rep. 2024; 14(1):5772.

PMID: 38459204 PMC: 10923804. DOI: 10.1038/s41598-024-56212-0.

A Review of the Carbon-Based Solid Transducing Layer for Ion-Selective Electrodes.

Wang P, Liu H, Zhou S, Chen L, Yu S, Wei J Molecules. 2023; 28(14).

PMID: 37513374 PMC: 10384130. DOI: 10.3390/molecules28145503.

TEER and Ion Selective Transwell-Integrated Sensors System for Caco-2 Cell Model.

Sciurti E, Blasi L, Prontera C, Barca A, Giampetruzzi L, Verri T Micromachines (Basel). 2023; 14(3).

PMID: 36984903 PMC: 10054836. DOI: 10.3390/mi14030496.

Carbon microelectrodes with customized shapes for neurotransmitter detection: A review.

Shao Z, Chang Y, Venton B Anal Chim Acta. 2022; 1223:340165.

PMID: 35998998 PMC: 9867599. DOI: 10.1016/j.aca.2022.340165.

References

Pergel E, Gyurcsanyi R, Toth K, Lindner E . Picomolar detection limits with current-polarized Pb2+ ion-selective membranes. Anal Chem. 2001; 73(17):4249-53. DOI: 10.1021/ac010094a. View

Makarychev-Mikhailov S, Shvarev A, Bakker E . Pulstrodes: triple pulse control of potentiometric sensors. J Am Chem Soc. 2004; 126(34):10548-9. DOI: 10.1021/ja047728q. View

Ammann D, Lanter F, Steiner R, Schulthess P, Shijo Y, Simon W . Neutral carrier based hydrogen ion selective microelectrode for extra- and intracellular studies. Anal Chem. 1981; 53(14):2267-9. DOI: 10.1021/ac00237a031. View

Afkhami A, Khoshsafar H, Bagheri H, Madrakian T . Construction of a carbon ionic liquid paste electrode based on multi-walled carbon nanotubes-synthesized Schiff base composite for trace electrochemical detection of cadmium. Mater Sci Eng C Mater Biol Appl. 2014; 35:8-14. DOI: 10.1016/j.msec.2013.10.025. View

Gyurcsanyi R, Pergel E, Nagy R, Kapui I, Lan B, Toth K . Direct evidence of ionic fluxes across ion-selective membranes: a scanning electrochemical microscopic and potentiometric study. Anal Chem. 2001; 73(9):2104-11. DOI: 10.1021/ac000922k. View

Harris D, Ummadi J, Thurber A, Allau Y, Verba C, Colwell F . Real-time monitoring of calcification process by Sporosarcina pasteurii biofilm. Analyst. 2016; 141(10):2887-95. DOI: 10.1039/c6an00007j. View

Crespo G, Macho S, Rius F . Ion-selective electrodes using carbon nanotubes as ion-to-electron transducers. Anal Chem. 2008; 80(4):1316-22. DOI: 10.1021/ac071156l. View

Peshkova M, Sokalski T, Mikhelson K, Lewenstam A . Obtaining Nernstian response of a Ca(2+)-selective electrode in a broad concentration range by tuned galvanostatic polarization. Anal Chem. 2009; 80(23):9181-7. DOI: 10.1021/ac8013143. View

Lai C, Fierke M, Stein A, Buhlmann P . Ion-selective electrodes with three-dimensionally ordered macroporous carbon as the solid contact. Anal Chem. 2007; 79(12):4621-6. DOI: 10.1021/ac070132b. View

10.

Bakker E, Buhlmann P, Pretsch E . Carrier-Based Ion-Selective Electrodes and Bulk Optodes. 1. General Characteristics. Chem Rev. 2002; 97(8):3083-3132. DOI: 10.1021/cr940394a. View

11.

Labar C, Lamberts L . Anodic stripping voltammetry with carbon paste electrodes for rapid Ag(I) and Cu(II) determinations. Talanta. 1997; 44(5):733-42. DOI: 10.1016/s0039-9140(96)02053-x. View

12.

Ummadi J, Downs C, Joshi V, Ferracane J, Koley D . Carbon-Based Solid-State Calcium Ion-Selective Microelectrode and Scanning Electrochemical Microscopy: A Quantitative Study of pH-Dependent Release of Calcium Ions from Bioactive Glass. Anal Chem. 2016; 88(6):3218-26. PMC: 4873256. DOI: 10.1021/acs.analchem.5b04614. View

13.

Trnkova L, Zerzankova L, Dycka F, Mikelova R, Jelen F . Study of Copper and Purine-Copper Complexes on Modified Carbon Electrodes by Cyclic and Elimination Voltammetry. Sensors (Basel). 2016; 8(1):429-444. PMC: 3681135. DOI: 10.3390/s8010429. View

14.

Joshi V, Sheet P, Cullin N, Kreth J, Koley D . Real-Time Metabolic Interactions between Two Bacterial Species Using a Carbon-Based pH Microsensor as a Scanning Electrochemical Microscopy Probe. Anal Chem. 2017; 89(20):11044-11052. PMC: 6265524. DOI: 10.1021/acs.analchem.7b03050. View

15.

Shvarev A, Bakker E . Reversible electrochemical detection of nonelectroactive polyions. J Am Chem Soc. 2005; 125(37):11192-3. DOI: 10.1021/ja037167n. View

16.

Krol A, Mizerna K, Bozym M . An assessment of pH-dependent release and mobility of heavy metals from metallurgical slag. J Hazard Mater. 2019; 384:121502. DOI: 10.1016/j.jhazmat.2019.121502. View

17.

Aponso S, Ummadi J, Davis H, Ferracane J, Koley D . A Chemical Approach to Optimizing Bioactive Glass Dental Composites. J Dent Res. 2018; 98(2):194-199. PMC: 6761734. DOI: 10.1177/0022034518809086. View

18.

Lisak G, Sokalski T, Bobacka J, Harju L, Mikhelson K, Lewenstam A . Tuned galvanostatic polarization of solid-state lead-selective electrodes for lowering of the detection limit. Anal Chim Acta. 2011; 707(1-2):1-6. DOI: 10.1016/j.aca.2011.09.026. View