Metamorphosis of Heterostructured Surface-Mounted Metal-Organic Frameworks Yielding Record Oxygen Evolution Mass Activities

Overview

Journal Adv Mater

Date 2021 Aug 2

PMID 34337809

Citations 7

Authors

Shujin Hou

Weijin Li

Sebastian Watzele

Regina M Kluge

Song Xue

Shanshan Yin

Xinyu Jiang

Markus Doblinger

Alexander Welle

Batyr Garlyyev

Max Koch

Peter Muller-Buschbaum

Christof Woll

Aliaksandr S Bandarenka

Roland A Fischer

Affiliations

Soon will be listed here.

Abstract

Materials derived from surface-mounted metal-organic frameworks (SURMOFs) are promising electrocatalysts for the oxygen evolution reaction (OER). A series of mixed-metal, heterostructured SURMOFs is fabricated by the facile layer-by-layer deposition method. The obtained materials reveal record-high electrocatalyst mass activities of ≈2.90 kA g at an overpotential of 300 mV in 0.1 m KOH, superior to the benchmarking precious and nonprecious metal electrocatalysts. This property is assigned to the particular in situ self-reconstruction and self-activation of the SURMOFs during the immersion and the electrochemical treatment in alkaline aqueous electrolytes, which allows for the generation of NiFe (oxy)hydroxide electrocatalyst materials of specific morphology and microstructure.

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