Molybdenum Disulfide-graphene Oxide Composites As Dispersive Solid-phase Extraction Adsorbents for the Enrichment of Four Paraben Preservatives in Cosmetics

Overview

Journal Mikrochim Acta

Specialties Biotechnology
Chemistry

Date 2021 Jul 16

PMID 34268616

Citations 2

Authors

Wenjing Sun

Xiaoyu Hu

Xiaoyang Meng

Yuhong Xiang

Nengsheng Ye

Affiliations

Soon will be listed here.

Abstract

Molybdenum disulfide-graphene oxide composite (MoS/GO) was synthesized and used as the adsorbent in dispersive solid-phase extraction. Four paraben preservatives, namely, methylparaben, ethylparaben, propylparaben, and butylparaben, were enriched with MoS/GO and determined by ultra-high-performance liquid chromatography. Molybdenum disulfide was intercalated into graphene oxide layers to reduce self-aggregation by using the solvothermal method. The experimental results indicated that the as-prepared MoS/GO composite exhibited great enrichment capability toward those four paraben preservatives, and the adsorption time was 10 min and the elution time was as short as 1 min. The mechanism of MoS/GO composite and parabens is attributed to hydrogen bonding and electrostatic attraction. The relative standard deviation (RSD, n = 9) of this method was below 7.6%. Limits of detection and limits of quantification were in the range 0.4-2.3 ng/mL and 1.4-7.6 ng/mL, respectively. The recoveries obtained from the parabens of cosmetic sample were in the range 91.3-124% with RSDs below 10%. The developed method has great potential for the determination of emerging contaminants with low cost and high sensitivity.

Citing Articles

[Recent advances in the use of graphene for sample preparation].

Feng J, Sun M, Feng Y, Xin X, Ding Y, Sun M Se Pu. 2022; 40(11):953-965.

PMID: 36351804 PMC: 9654959. DOI: 10.3724/SP.J.1123.2022.07012.

Nanomaterials with Excellent Adsorption Characteristics for Sample Pretreatment: A Review.

Liu W, Song S, Ye M, Zhu Y, Zhao Y, Lu Y Nanomaterials (Basel). 2022; 12(11).

PMID: 35683700 PMC: 9182308. DOI: 10.3390/nano12111845.

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