One-Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening

Overview

Journal ChemistryOpen

Specialty Chemistry

Date 2021 Apr 28

PMID 33908706

Citations 2

Authors

Matthieu Pelingre

Meriem Smadhi

Abed Bil

Veronique Bonnet

Jose Kovensky

Affiliations

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Abstract

The synthesis of pure difunctionalized hexa-, hepta- and octamaltosides was performed by one-pot chemical reaction from perbenzoylated cyclodextrin. Oligomaltosides with azide, propargyl or allyl on reducing end and an unprotected hydroxyl group on non-reducing end were obtained from perbenzoylated α-, β- and γ-cyclodextrin with 12 to 48 % yields.

Citing Articles

Site-Selective Modification of (Oligo)Saccharides.

Witte M, Minnaard A ACS Catal. 2022; 12(19):12195-12205.

PMID: 36249871 PMC: 9552177. DOI: 10.1021/acscatal.2c03876.

One-Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening.

Pelingre M, Smadhi M, Bil A, Bonnet V, Kovensky J ChemistryOpen. 2021; 10(4):493-496.

PMID: 33908706 PMC: 8080284. DOI: 10.1002/open.202100079.

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