Intermolecular Hydroaminoalkylation of Propadiene

Overview

Journal Chemistry

Specialty Chemistry

Date 2020 Aug 27

PMID 32844473

Citations 5

Authors

Tobias Kaper

Malte Fischer

Michael Warsitz

Rene Zimmering

Ruediger Beckhaus

Sven Doye

Affiliations

Soon will be listed here.

Abstract

Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6-bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium-carbon bond of a titanaaziridine.

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Titanium-Catalyzed Intermolecular Hydroaminoalkylation of Alkenes with Tertiary Amines.

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Intermolecular Hydroaminoalkylation of Alkynes.

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Intermolecular Hydroaminoalkylation of Propadiene.

Kaper T, Fischer M, Warsitz M, Zimmering R, Beckhaus R, Doye S Chemistry. 2020; 26(63):14300-14304.

PMID: 32844473 PMC: 7702142. DOI: 10.1002/chem.202003484.

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