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Analytical Method Validation, Dissipation and Safety Evaluation of Combination Fungicides Fenamidone + mancozeb and Iprovalicarb + propineb In/on Tomato

Overview
Journal J Food Sci Technol
Specialty Nutritional Sciences
Date 2020 May 21
PMID 32431332
Citations 2
Authors
Yengkhom Bijen Kumar
T P Ahammed Shabeer
Manjusha Jadhav
Kaushik Banerjee
Sandip Hingmire
Sujoy Saha
Awadhesh Bahadur Rai
Affiliations
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Abstract

Dissipation behavior and degradation kinetics of fenamidone + mancozeb (Sectin 60 WG) and iprovalicarb + propineb (Melody Duo 66.75 WP) in tomato were studied at recommended dose (RD) and double dose (DD) of application. The analysis of the field samples were carried out by employing liquid chromatography tandem mass spectrometry (LC-MS/MS) for fenamidone and iprovalicarb residues and gas chromatography mass spectrometry for mancozeb and propineb residues after thorough validation of the extraction methods. The dissipation of residues best followed 1st + 1st order for all the test fungicides. The half-life period for fenamidone, mancozeb, iprovalicarb and propineb were 2, 2, 1.5 and 2 days for RD and 3, 2.5, 2 and 3 days for DD, respectively. The pre-harvest intervals were not applicable for iprovalicarb, fenamidone and mancozeb (at RD) as the residues at 0 day were below maximum residue limit set by European Union, and it was 1 day for DD of iprovalicarb, 3.5 days for DD of fenamidone, 3 days for DD of mancozeb, 3 and 7 days for propineb at RD and DD, respectively. A PHI of 4 and 7 days are proposed for fenamidone + Mancozeb and iprovalicarb + propineb, respectively. Dietary exposure calculated for all the pesticides were safe on all the sampling days except for propineb residues for which it was safe after first day of the double dose application. The study will be useful for promoting effective residue management and safe use of these chemicals for controlling fungal diseases in tomato crop.

Citing Articles

Analysis, residue behaviour and risk assessment of combination product of iprovalicarb + copper oxychloride in representative fruiting vegetables, cucurbit and in soil using LC-MS/MS and ICP-MS.

Kalasariya R, Chaudhary N, Patel M, Chawla S, Parmar K, Rathod P Environ Sci Pollut Res Int. 2024; 31(10):15186-15198.

PMID: 38291206 DOI: 10.1007/s11356-024-32135-1.

Interaction between Six Waxy Components in Summer Black Grapes () and Mancozeb and Its Effect on the Residue of Mancozeb.

Guo B, Wen A, Yu H, Guo Y, Cheng Y, Xie Y Int J Mol Sci. 2023; 24(9).

PMID: 37175414 PMC: 10178566. DOI: 10.3390/ijms24097705.

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