Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO Using a Molecular Cobalt(II) Triazine Complex

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2020 Apr 29

PMID 32343876

Citations 14

Authors

Hanna H Cramer

Basujit Chatterjee

Thomas Weyhermuller

Christophe Werle

Walter Leitner

Affiliations

Soon will be listed here.

Abstract

The catalytic reduction of carbon dioxide (CO ) is considered a major pillar of future sustainable energy systems and chemical industries based on renewable energy and raw materials. Typically, catalysts and catalytic systems are transforming CO preferentially or even exclusively to one of the possible reduction levels and are then optimized for this specific product. Here, we report a cobalt-based catalytic system that enables the adaptive and highly selective transformation of carbon dioxide individually to either the formic acid, the formaldehyde, or the methanol level, demonstrating the possibility of molecular control over the desired product platform.

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