A Sterically Congested Nitrogenated Benzodipentaphene with a Double π-Expanded Helicene Structure

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2020 Apr 16

PMID 32290661

Citations 7

Authors

Fengkun Chen

Wenting Gu

Akinori Saeki

Manuel Melle-Franco

Aurelio Mateo-Alonso

Affiliations

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Abstract

Herein, we describe a series of three sterically congested nitrogenated benzodipentaphenes, one of which shows a highly distorted aromatic backbone with an unprecedented double π-expanded helicene structure.

Citing Articles

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Marongiu M, Ha T, Gil-Guerrero S, Garg K, Mandado M, Melle-Franco M J Am Chem Soc. 2024; 146(6):3963-3973.

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Design and Synthesis of a Polyketone Building Block with Vinyl Groups-9,10-Diethyl-9,10-ethenoanthracene-2,3,6,7(9,10)-tetraone-and a Preliminary Photoelectrical Property Study of Its Azaacene Derivatives.

Chen H, Zhang S, Liu J, Li J, Chen W, Zhou G ACS Omega. 2023; 8(36):32931-32939.

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Planar and Helical Dinaphthophenazines.

Chen F, Melle-Franco M, Mateo-Alonso A J Org Chem. 2022; 87(12):7635-7642.

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Doubling the Length of the Longest Pyrene-Pyrazinoquinoxaline Molecular Nanoribbons.

Hernandez-Culebras F, Melle-Franco M, Mateo-Alonso A Angew Chem Int Ed Engl. 2022; 61(27):e202205018.

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Inducing Single-Handed Helicity in a Twisted Molecular Nanoribbon.

Dubey R, Melle-Franco M, Mateo-Alonso A J Am Chem Soc. 2022; 144(6):2765-2774.

PMID: 35099195 PMC: 8855342. DOI: 10.1021/jacs.1c12385.