Nanocarbon Catalysts: Recent Understanding Regarding the Active Sites

Overview

Journal Adv Sci (Weinh)

Specialty Biomedical Engineering

Date 2020 Mar 11

PMID 32154069

Citations 15

Authors

Lu-Hua Zhang

Yumeng Shi

Ye Wang

N Raveendran Shiju

Affiliations

Soon will be listed here.

Abstract

Although carbon itself acts as a catalyst in various reactions, the classical carbon materials (e.g., activated carbons, carbon aerogels, carbon black, carbon fiber, etc.) usually show low activity, stability, and oxidation resistance. With the recent availability of nanocarbon catalysts, the application of carbon materials in catalysis has gained a renewed momentum. The research is concentrated on tailoring the surface chemistry of nanocarbon materials, since the pristine carbons in general are not active for heterogeneous catalysis. Surface functionalization, doping with heteroatoms, and creating defects are the most used strategies to make efficient catalysts. However, the nature of the catalytic active sites and their role in determining the activity and selectivity is still not well understood. Herein, the types of active sites reported for several mainstream nanocarbons, including carbon nanotubes, graphene-based materials, and 3D porous nanocarbons, are summarized. Knowledge about the active sites will be beneficial for the design and synthesis of nanocarbon catalysts with improved activity, selectivity, and stability.

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References

Chen W, Pei J, He C, Wan J, Ren H, Zhu Y . Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction. Angew Chem Int Ed Engl. 2017; 56(50):16086-16090. DOI: 10.1002/anie.201710599. View

Yadav R, Wu J, Kochandra R, Ma L, Tiwary C, Ge L . Carbon Nitrogen Nanotubes as Efficient Bifunctional Electrocatalysts for Oxygen Reduction and Evolution Reactions. ACS Appl Mater Interfaces. 2015; 7(22):11991-2000. DOI: 10.1021/acsami.5b02032. View

Novoselov K, Geim A, Morozov S, Jiang D, Zhang Y, Dubonos S . Electric field effect in atomically thin carbon films. Science. 2004; 306(5696):666-9. DOI: 10.1126/science.1102896. View

Jia Y, Zhang L, Du A, Gao G, Chen J, Yan X . Defect Graphene as a Trifunctional Catalyst for Electrochemical Reactions. Adv Mater. 2016; 28(43):9532-9538. DOI: 10.1002/adma.201602912. View

Gao Y, Tang P, Zhou H, Zhang W, Yang H, Yan N . Graphene Oxide Catalyzed C-H Bond Activation: The Importance of Oxygen Functional Groups for Biaryl Construction. Angew Chem Int Ed Engl. 2016; 55(9):3124-8. DOI: 10.1002/anie.201510081. View

Tison Y, Lagoute J, Repain V, Chacon C, Girard Y, Rousset S . Electronic interaction between nitrogen atoms in doped graphene. ACS Nano. 2015; 9(1):670-8. DOI: 10.1021/nn506074u. View

He M, Zhou S, Zhang J, Liu Z, Robinson C . CVD growth of N-doped carbon nanotubes on silicon substrates and its mechanism. J Phys Chem B. 2006; 109(19):9275-9. DOI: 10.1021/jp044868d. View

Yan H, Cheng H, Yi H, Lin Y, Yao T, Wang C . Single-Atom Pd₁/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene. J Am Chem Soc. 2015; 137(33):10484-7. DOI: 10.1021/jacs.5b06485. View

Varela A, Ranjbar Sahraie N, Steinberg J, Ju W, Oh H, Strasser P . Metal-Doped Nitrogenated Carbon as an Efficient Catalyst for Direct CO2 Electroreduction to CO and Hydrocarbons. Angew Chem Int Ed Engl. 2015; 54(37):10758-62. DOI: 10.1002/anie.201502099. View

10.

Karousis N, Tagmatarchis N, Tasis D . Current progress on the chemical modification of carbon nanotubes. Chem Rev. 2010; 110(9):5366-97. DOI: 10.1021/cr100018g. View

11.

Nekoueian K, Amiri M, Sillanpaa M, Marken F, Boukherroub R, Szunerits S . Carbon-based quantum particles: an electroanalytical and biomedical perspective. Chem Soc Rev. 2019; 48(15):4281-4316. DOI: 10.1039/c8cs00445e. View

12.

Jeon I, Zhang S, Zhang L, Choi H, Seo J, Xia Z . Edge-selectively sulfurized graphene nanoplatelets as efficient metal-free electrocatalysts for oxygen reduction reaction: the electron spin effect. Adv Mater. 2013; 25(42):6138-45. DOI: 10.1002/adma.201302753. View

13.

Cui W, Liu Q, Cheng N, Asiri A, Sun X . Activated carbon nanotubes: a highly-active metal-free electrocatalyst for hydrogen evolution reaction. Chem Commun (Camb). 2014; 50(66):9340-2. DOI: 10.1039/c4cc02713b. View

14.

Jeon I, Choi H, Choi M, Seo J, Jung S, Kim M . Facile, scalable synthesis of edge-halogenated graphene nanoplatelets as efficient metal-free eletrocatalysts for oxygen reduction reaction. Sci Rep. 2013; 3:1810. PMC: 3672906. DOI: 10.1038/srep01810. View

15.

Yan Y, Miao J, Yang Z, Xiao F, Yang H, Liu B . Carbon nanotube catalysts: recent advances in synthesis, characterization and applications. Chem Soc Rev. 2015; 44(10):3295-346. DOI: 10.1039/c4cs00492b. View

16.

Lu A, Sun T, Li W, Sun Q, Han F, Liu D . Synthesis of discrete and dispersible hollow carbon nanospheres with high uniformity by using confined nanospace pyrolysis. Angew Chem Int Ed Engl. 2011; 50(49):11765-8. DOI: 10.1002/anie.201105486. View

17.

Tang C, Zhang Q . Nanocarbon for Oxygen Reduction Electrocatalysis: Dopants, Edges, and Defects. Adv Mater. 2017; 29(13). DOI: 10.1002/adma.201604103. View

18.

Chung H, Cullen D, Higgins D, Sneed B, Holby E, More K . Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst. Science. 2017; 357(6350):479-484. DOI: 10.1126/science.aan2255. View

19.

Zhu C, Li H, Fu S, Du D, Lin Y . Highly efficient nonprecious metal catalysts towards oxygen reduction reaction based on three-dimensional porous carbon nanostructures. Chem Soc Rev. 2015; 45(3):517-31. DOI: 10.1039/c5cs00670h. View

20.

Wang X, Li X, Zhang L, Yoon Y, Weber P, Wang H . N-doping of graphene through electrothermal reactions with ammonia. Science. 2009; 324(5928):768-71. DOI: 10.1126/science.1170335. View