Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2020 Feb 25

PMID 32091647

Citations 10

Authors

Man-Bo Li

Ying Yang

Abdolrahim A Rafi

Michael Oschmann

Erik Svensson Grape

A Ken Inge

Armando Cordova

Jan-E Backvall

Affiliations

Soon will be listed here.

Abstract

A silver-triggered heterogeneous Pd-catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one-pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd-AmP-CNC, thereby generating highly active Pd , which results in high efficiency of the heterogeneous catalytic system.

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