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Fluorescent Fluid in 3D-Printed Microreactors for the Acceleration of Photocatalytic Reactions

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Journal Adv Sci (Weinh)
Date 2019 Aug 6
PMID 31380193
Citations 5
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Abstract

The photochemical microreactor has been a burgeoning field with important application in promoting photocatalytic reactions. The integration of light-converting media and microflow chemistry renders new opportunity for efficient utilization of light and high conversion rate. However, the flexibility of emission light wavelength regulation and the universality of the microreactor remain significant problems to be solved. Here, a photochemical microreactor filled with fluorescent fluid is fabricated by a 3D printing technique. The light-converting medium in the fluorescent fluid is used to collect and convert light, and then delivers light energy to the embedded continuous-flow reaction channels to promote the chemical reaction process. With the merits of flowability, different light-converting media can be replaced, making it a general tool for photocatalytic reactions in rapid screening, parameters optimization, and kinetic mechanism research.

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References
1.
Zou Q, Liu K, Abbas M, Yan X . Peptide-Modulated Self-Assembly of Chromophores toward Biomimetic Light-Harvesting Nanoarchitectonics. Adv Mater. 2015; 28(6):1031-43. DOI: 10.1002/adma.201502454. View

2.
Zhao F, Cambie D, Janse J, Wieland E, Kuijpers K, Hessel V . Scale-up of a Luminescent Solar Concentrator-Based Photomicroreactor via Numbering-up. ACS Sustain Chem Eng. 2018; 6(1):422-429. PMC: 5762165. DOI: 10.1021/acssuschemeng.7b02687. View

3.
Chen P, Weng Y, Niu L, Chen Y, Wu L, Tung C . Light-Harvesting Systems Based on Organic Nanocrystals To Mimic Chlorosomes. Angew Chem Int Ed Engl. 2016; 55(8):2759-63. DOI: 10.1002/anie.201510503. View

4.
Thomas M, Millare B, Clift J, Bao D, Hong C, Vullev V . Print-and-peel fabrication for microfluidics: what's in it for biomedical applications?. Ann Biomed Eng. 2009; 38(1):21-32. PMC: 2803264. DOI: 10.1007/s10439-009-9831-x. View

5.
Le C, Wismer M, Shi Z, Zhang R, Conway D, Li G . A General Small-Scale Reactor To Enable Standardization and Acceleration of Photocatalytic Reactions. ACS Cent Sci. 2017; 3(6):647-653. PMC: 5492256. DOI: 10.1021/acscentsci.7b00159. View