Liquid Marble-derived Solid-liquid Hybrid Superparticles for CO Capture

Overview

Journal Nat Commun

Specialty Biology

Date 2019 Apr 25

PMID 31015427

Citations 5

Authors

Xia Rong

Rammile Ettelaie

Sergey V Lishchuk

Huaigang Cheng

Ning Zhao

Fukui Xiao

Fangqin Cheng

Hengquan Yang

Affiliations

Soon will be listed here.

Abstract

The design of effective CO capture materials is an ongoing challenge. Here we report a concept to overcome current limitations associated with both liquid and solid CO capture materials by exploiting a solid-liquid hybrid superparticle (SLHSP). The fabrication of SLHSP involves assembly of hydrophobic silica nanoparticles on the liquid marble surface, and co-assembly of hydrophilic silica nanoparticles and tetraethylenepentamine within the interior of the liquid marble. The strong interfacial adsorption force and the strong interactions between amine and silica are identified to be key elements for high robustness. The developed SLHSPs exhibit excellent CO sorption capacity, high sorption rate, long-term stability and reduced amine loss in industrially preferred fixed bed setups. The outstanding performances are attributed to the unique structure which hierarchically organizes the liquid and solid at microscales.

Citing Articles

Atom-level interaction design between amines and support for achieving efficient and stable CO capture.

Sun X, Shen X, Wang H, Yan F, Hua J, Li G Nat Commun. 2024; 15(1):5068.

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Biocompatible Hydrogel-Based Liquid Marbles with Magnetosomes.

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Controllable Construction of Amino-Functionalized Dynamic Covalent Porous Polymers for High-Efficiency CO Capture from Flue Gas.

Qiu M, Wu H, Huang Y, Guo H, Gao D, Pei F Molecules. 2022; 27(18).

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Influence of water evaporation/absorption on the stability of glycerol-water marbles.

Lin X, Ma W, Chen L, Huang L, Wu H, Takahara A RSC Adv. 2022; 9(59):34465-34471.

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