Elucidating the Mechanism of the Structure-dependent Enzymatic Activity of Fe-N/C Oxidase Mimics

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2019 Apr 18

PMID 30993298

Citations 13

Authors

Ying Wang

Ziwei Zhang

Guangri Jia

Lirong Zheng

Jingxiang Zhao

Xiaoqiang Cui

Affiliations

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Abstract

Herein, we develop an Fe-N/C-CNT nanomaterial with Fe-N units as a paradigm for excellent oxidase mimics by theoretical prediction and experimental implementation. The mechanism of the structure-dependent enzymatic activity is systematically investigated and elucidated from the perspective of the different configurations of M-N models (x = 0, 3, 4, and 5; M = Fe, Co, and Ni).

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