Efficacy of Engineered GO Amberlite XAD-16 Picolylamine Sorbent for the Trace Determination of Pb (II) and Cu (II) in Fishes by Solid Phase Extraction Column Coupled with Inductively Coupled Plasma Optical Emission Spectrometry

Overview

Journal Sci Rep

Specialty Science

Date 2018 Dec 5

PMID 30510289

Citations 7

Authors

Hina Javed

Aminul Islam

Anjali Chauhan

Suneel Kumar

Sushil Kumar

Affiliations

Soon will be listed here.

Abstract

Graphene oxide (GO) was immobilized innovatively through azo spacer arm onto the surface of polymeric Amberlite XAD-16 resin in order to expose all oxygen functionalities freely available for metal ions coordination and further modification with picolylamine which governs selectivity. The GO Amberlite XAD-16 picolylamine enables the development of SPE column coupled with ICP-OES for preconcentration and determination of Pb (II) and Cu (II) in water and fish samples. Elution was performed by mild acid (2M HCl) no other carcinogenic organic solvent was used, prevents ligand leaching. Under optimized conditions, the preconcentration factors of 150 and detection limits 1.434 and 0.048 µg L for Pb (II) and Cu (II) were obtained respectively.

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