Covalently Modified Graphene Oxide and Polymer of Intrinsic Microporosity (PIM-1) in Mixed Matrix Thin-Film Composite Membranes

Overview

Journal Nanoscale Res Lett

Publisher Springer

Specialty Biotechnology

Date 2018 Nov 14

PMID 30421344

Citations 6

Authors

Elvin M Aliyev

Muntazim Munir Khan

Afig M Nabiyev

Rasim M Alosmanov

Irada A Bunyad-Zadeh

Sergey Shishatskiy

Volkan Filiz

Affiliations

Soon will be listed here.

Abstract

In this study, mixed matrix membranes (MMMs) consisting of graphene oxide (GO) and functionalized graphene oxide (FGO) incorporated in a polymer of intrinsic microporosity (PIM-1) serving as a polymer matrix have been fabricated by dip-coating method, and their single gas transport properties were investigated. Successfully surface-modified GOs were characterized by Fourier transform infrared spectroscopy (FTIR), UV-Vis spectroscopy, Raman spectroscopy, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The effect of FGO loading on MMM morphology and performance was investigated by varying the FGO content in polymer matrix from 9 to 84 wt.%. Use of high FGO content in the polymer matrix helped to reveal difference in interaction of functionalized fillers with PIM-1 and even to discuss the change of FGO stiffness and filler alignment to the membrane surface depending on functional group nature.

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