Thickness-dependent Thermoelectric Power Factor of Polymer-functionalized Semiconducting Carbon Nanotube Thin Films
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The effects of polymer structures on the thermoelectric properties of polymer-wrapped semiconducting carbon nanotubes have yet to be clarified for elucidating intrinsic transport properties. We systematically investigate thickness dependence of thermoelectric transport in thin films containing networks of conjugated polymer-wrapped semiconducting carbon nanotubes. Well-controlled doping experiments suggest that the doping homogeneity and then in-plane electrical conductivity significantly depend on film thickness and polymer species. This understanding leads to achieving thermoelectric power factors as high as 412 μW m K in thin carbon nanotube films. This work presents a standard platform for investigating the thermoelectric properties of nanotubes.
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PMID: 38654020 PMC: 11039726. DOI: 10.1038/s41467-024-47417-y.
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PMID: 36677122 PMC: 9865119. DOI: 10.3390/mi14010061.