Rh-Catalyzed Annulations of N-methoxybenzamides with Ketenimines: Synthesis of 3-aminoisoindolinones and 3-diarylmethyleneisoindolinones with Strong Aggregation Induced Emission Properties

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2016 Aug 11

PMID 27507583

Citations 3

Authors

Xiaorong Zhou

Zhixing Peng

Hongyang Zhao

Zhiyin Zhang

Ping Lu

Yanguang Wang

Affiliations

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Abstract

Rhodium-catalyzed C-H activation/annulation reactions of ketenimines with N-methoxybenzamides furnished 3-aminoisoindolin-1-ones and 3-(diarylmethylene)isoindolin-1-ones. The synthesized 3-(diarylmethylene)isoindolin-1-ones exhibited aggregation induced emissions in aqueous tetrahydrofuran solution and strong green-yellow emissions in solids.

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