Electron-Phonon Coupling Strength at Metal Surfaces Directly Determined from the Helium Atom Scattering Debye-Waller Factor

A new quantum-theoretical derivation of the elastic and inelastic scattering probability of He atoms from a metal surface, where the energy and momentum exchange with the phonon gas can occur only through the mediation of the surface free-electron density, shows that the Debye-Waller exponent is directly proportional to the electron-phonon mass coupling constant λ. The comparison between the values of λ extracted from existing data on the Debye-Waller factor for various metal surfaces and the λ values known from literature indicates a substantial agreement, which opens the possibility of directly extracting the electron-phonon coupling strength in quasi-2D conducting systems from the temperature or incident energy dependence of the elastic helium atom scattering intensities.