Crystal Structure of 2-{[2-meth-oxy-5-(tri-fluoro-meth-yl)phen-yl]iminomethyl}-4-nitro-phenol
Overview
Affiliations
In the title compound, C15H11F3N2O4, the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intra-molecular bifurcated O-H⋯(N,O) hydrogen bond with S(6) and S(9) ring motifs. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds into a helical chain along the 31 screw axis parallel to c. The -CF3 group shows rotational disorder over two sites, with occupancies of 0.39 (2) and 0.61 (2).
Faizi M, Cinar E, Dogan O, Aydin A, Agar E, Dege N Acta Crystallogr E Crystallogr Commun. 2020; 76(Pt 8):1325-1330.
PMID: 32844023 PMC: 7405564. DOI: 10.1107/S2056989020009615.
()-3-({[3-Meth-oxy-5-(tri-fluoro-meth-yl)phen-yl]imino}meth-yl)benzene-1,2-diol.
Demir Kanmazalp S, Dogan O, Dege N, Agar E, Bulbul H, Golenya I Acta Crystallogr E Crystallogr Commun. 2019; 75(Pt 4):470-474.
PMID: 31161059 PMC: 6509687. DOI: 10.1107/S2056989019003220.