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Crystal Structure of 2-{[2-meth-oxy-5-(tri-fluoro-meth-yl)phen-yl]iminomethyl}-4-nitro-phenol

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Date 2015 Aug 18
PMID 26279911
Citations 2
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Abstract

In the title compound, C15H11F3N2O4, the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intra-molecular bifurcated O-H⋯(N,O) hydrogen bond with S(6) and S(9) ring motifs. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds into a helical chain along the 31 screw axis parallel to c. The -CF3 group shows rotational disorder over two sites, with occupancies of 0.39 (2) and 0.61 (2).

Citing Articles

Crystal structure, Hirshfeld surface analysis and DFT studies of 4-methyl-2-({[4-(tri-fluoro-meth-yl)phen-yl]imino}-meth-yl)phenol.

Faizi M, Cinar E, Dogan O, Aydin A, Agar E, Dege N Acta Crystallogr E Crystallogr Commun. 2020; 76(Pt 8):1325-1330.

PMID: 32844023 PMC: 7405564. DOI: 10.1107/S2056989020009615.


()-3-({[3-Meth-oxy-5-(tri-fluoro-meth-yl)phen-yl]imino}meth-yl)benzene-1,2-diol.

Demir Kanmazalp S, Dogan O, Dege N, Agar E, Bulbul H, Golenya I Acta Crystallogr E Crystallogr Commun. 2019; 75(Pt 4):470-474.

PMID: 31161059 PMC: 6509687. DOI: 10.1107/S2056989019003220.

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