Frustrated Lewis Pairs: a Metal-free Landmark

Overview

Journal Nat Chem

Specialty Chemistry

Date 2014 Oct 25

PMID 25343596

Citations 3

Authors

Douglas W Stephan

Affiliations

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Citing Articles

The Lewis superacid Al[N(CF)] and its higher homolog Ga[N(CF)] - structural features, theoretical investigation and reactions of a metal amide with higher fluoride ion affinity than SbF.

Kogel J, Sorokin D, Khvorost A, Scott M, Harms K, Himmel D Chem Sci. 2018; 9(1):245-253.

PMID: 29629094 PMC: 5869307. DOI: 10.1039/c7sc03988c.

Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids.

Lawrence E, Clark E, Curless L, Courtney J, Blagg R, Ingleson M Chem Sci. 2017; 7(4):2537-2543.

PMID: 28660024 PMC: 5477046. DOI: 10.1039/c5sc04564a.

Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO.

Zhang S, Huang Z, Ma Y, Gao W, Li J, Cao F Nat Commun. 2017; 8:15266.

PMID: 28516952 PMC: 5454379. DOI: 10.1038/ncomms15266.

References

Rendler S, Oestreich M . Conclusive evidence for an S(N)2-Si mechanism in the B(C6F5)3-catalyzed hydrosilylation of carbonyl compounds: implications for the related hydrogenation. Angew Chem Int Ed Engl. 2008; 47(32):5997-6000. DOI: 10.1002/anie.200801675. View

Stephan D, Erker G . Frustrated lewis pair mediated hydrogenations. Top Curr Chem. 2013; 332:85-110. DOI: 10.1007/128_2012_392. View

Houghton A, Hurmalainen J, Mansikkamaki A, Piers W, Tuononen H . Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations. Nat Chem. 2014; 6(11):983-8. DOI: 10.1038/nchem.2063. View

Houghton A, Karttunen V, Piers W, Tuononen H . Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene. Chem Commun (Camb). 2013; 50(11):1295-8. DOI: 10.1039/c3cc48796b. View

Stephan D, Erker G . Frustrated Lewis pairs: metal-free hydrogen activation and more. Angew Chem Int Ed Engl. 2009; 49(1):46-76. DOI: 10.1002/anie.200903708. View