Preparation of Chitosan Coated Magnetic Hydroxyapatite Nanoparticles and Application for Adsorption of Reactive Blue 19 and Ni2+ Ions

Overview

Journal ScientificWorldJournal

Publisher Wiley

Specialty Biology

Date 2014 Mar 5

PMID 24592158

Citations 9

Authors

Van Cuong Nguyen

Quoc Hue Pho

Affiliations

Soon will be listed here.

Abstract

An adsorbent called chitosan coated magnetic hydroxyapatite nanoparticles (CS-MHAP) was prepared with the purpose of improvement for the removal of Ni(2+) ions and textile dye by coprecipitation. Structure and properties of CS-MHAP were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and vibrating sample magnetometer (VSM). Weight percent of chitosan was investigated by thermal gravimetric analysis (TGA). The prepared CS-MHAP presents a significant improvement on the removal efficiency of Ni(2+) ions and reactive blue 19 dye (RB19) in comparison with chitosan and magnetic hydroxyapatite nanoparticles. Moreover, the adsorption capacities were affected by several parameters such as contact time, initial concentration, adsorbent dosage, and initial pH. Interestingly, the prepared adsorbent could be easily recycled from an aqueous solution by an external magnet and reused for adsorption with high removal efficiency.

Citing Articles

Study on the Performance of Coal Gangue-Loaded Hydroxyapatite (CG@HAP) for the Adsorption of Malachite Green.

Shao J, Wu D Molecules. 2024; 29(23).

PMID: 39683808 PMC: 11643914. DOI: 10.3390/molecules29235649.

Applications of Nano Hydroxyapatite as Adsorbents: A Review.

Balasooriya I, Chen J, Gedara S, Han Y, Wickramaratne M Nanomaterials (Basel). 2022; 12(14).

PMID: 35889550 PMC: 9319406. DOI: 10.3390/nano12142324.

Removal of U(vi) from aqueous solutions by an effective bio-adsorbent from walnut shell and cellulose composite-stabilized iron sulfide nanoparticles.

Hu Z, Wang H, Liu R, Hu B, Qiu M RSC Adv. 2022; 12(5):2675-2683.

PMID: 35425288 PMC: 8979344. DOI: 10.1039/d1ra08087c.

Chitosan-Terephthalic Acid-Magnetic Composite Beads for Effective Removal of the Acid Blue Dye from Aqueous Solutions: Kinetics, Isotherm, and Statistical Modeling.

Akinremi C, Adeogun A, Poupin M, Huddersman K ACS Omega. 2021; 6(45):30499-30514.

PMID: 34805679 PMC: 8600647. DOI: 10.1021/acsomega.1c03964.

Methylene Blue Dye Adsorption from Wastewater Using Hydroxyapatite/Gold Nanocomposite: Kinetic and Thermodynamics Studies.

Sharma K, Sharma S, Sharma V, Mishra P, Ekielski A, Sharma V Nanomaterials (Basel). 2021; 11(6).

PMID: 34073274 PMC: 8227305. DOI: 10.3390/nano11061403.

References

Fan J, Bi L, Wu T, Cao L, Wang D, Nan K . A combined chitosan/nano-size hydroxyapatite system for the controlled release of icariin. J Mater Sci Mater Med. 2011; 23(2):399-407. DOI: 10.1007/s10856-011-4491-4. View

Pavan F, Mazzocato A, Gushikem Y . Removal of methylene blue dye from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent. Bioresour Technol. 2007; 99(8):3162-5. DOI: 10.1016/j.biortech.2007.05.067. View

Jayakumar R, Prabaharan M, Sudheesh Kumar P, Nair S, Tamura H . Biomaterials based on chitin and chitosan in wound dressing applications. Biotechnol Adv. 2011; 29(3):322-37. DOI: 10.1016/j.biotechadv.2011.01.005. View

Jarup L . Hazards of heavy metal contamination. Br Med Bull. 2004; 68:167-82. DOI: 10.1093/bmb/ldg032. View

Oller I, Malato S, Sanchez-Perez J . Combination of Advanced Oxidation Processes and biological treatments for wastewater decontamination--a review. Sci Total Environ. 2010; 409(20):4141-66. DOI: 10.1016/j.scitotenv.2010.08.061. View

Chen L, Hu J, Shen X, Tong H . Synthesis and characterization of chitosan-multiwalled carbon nanotubes/hydroxyapatite nanocomposites for bone tissue engineering. J Mater Sci Mater Med. 2013; 24(8):1843-51. DOI: 10.1007/s10856-013-4954-x. View

Blackall L, Crocetti G, Saunders A, Bond P . A review and update of the microbiology of enhanced biological phosphorus removal in wastewater treatment plants. Antonie Van Leeuwenhoek. 2002; 81(1-4):681-91. DOI: 10.1023/a:1020538429009. View

Pavon-Silva T, Pacheco-Salazar V, Sanchez-Meza J, Roa-Morales G, Colin-Cruz A . Physicochemical and biological combined treatment applied to a food industry wastewater for reuse. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2008; 44(1):108-15. DOI: 10.1080/10934520802515467. View

Hu H, Xin J, Hu H, Chan A, He L . Glutaraldehyde-chitosan and poly (vinyl alcohol) blends, and fluorescence of their nano-silica composite films. Carbohydr Polym. 2012; 91(1):305-13. DOI: 10.1016/j.carbpol.2012.08.038. View

10.

Liao D, Zheng W, Li X, Yang Q, Yue X, Guo L . Removal of lead(II) from aqueous solutions using carbonate hydroxyapatite extracted from eggshell waste. J Hazard Mater. 2010; 177(1-3):126-30. DOI: 10.1016/j.jhazmat.2009.12.005. View

11.

Al Bakheet S, Attafi I, Maayah Z, Abd-Allah A, Asiri Y, Korashy H . Effect of long-term human exposure to environmental heavy metals on the expression of detoxification and DNA repair genes. Environ Pollut. 2013; 181:226-32. DOI: 10.1016/j.envpol.2013.06.014. View

12.

Rajiv Gandhi M, Kousalya G, Meenakshi S . Removal of copper(II) using chitin/chitosan nano-hydroxyapatite composite. Int J Biol Macromol. 2010; 48(1):119-24. DOI: 10.1016/j.ijbiomac.2010.10.009. View

13.

Sakkayawong N, Thiravetyan P, Nakbanpote W . Adsorption mechanism of synthetic reactive dye wastewater by chitosan. J Colloid Interface Sci. 2005; 286(1):36-42. DOI: 10.1016/j.jcis.2005.01.020. View