Preparation and Characterization of Alkenyl Aryl Tetrafluoro-λ(6) -sulfanes

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2013 Nov 29

PMID 24285622

Citations 10

Authors

Linbin Zhong

Paul R Savoie

Alexander S Filatov

John T Welch

Affiliations

Soon will be listed here.

Abstract

Substituted alkenyl aryl tetrafluoro-λ(6) -sulfanes have been prepared by the direct addition of readily accessible chlorotetrafluorosulfanyl arenes to primary alkynes. Substitution of an apical fluorine of the pentafluorosulfanyl group enables modulation of the reactivity of this little explored functional group while at the same time facilitating the direct investigation of aryl substituent effects on the aryl tetrafluorosulfanyl-substituted products.

Citing Articles

Photocurable Hypervalent Fluorinated Sulfur Containing Thin Films with Remarkable Hardness and Modulus.

Bonetti K, Rende D, Murphy M, Welch J Molecules. 2024; 29(18).

PMID: 39339408 PMC: 11434361. DOI: 10.3390/molecules29184413.

Overcoming a Radical Polarity Mismatch in Strain-Release Pentafluorosulfanylation of [1.1.0]Bicyclobutanes: An Entryway to Sulfone- and Carbonyl-Containing SF-Cyclobutanes.

Kraemer Y, Buldt J, Kong W, Stephens A, Ragan A, Park S Angew Chem Int Ed Engl. 2024; 63(19):e202319930.

PMID: 38237059 PMC: 11045327. DOI: 10.1002/anie.202319930.

Expanding the Frontier of Linear Drug Design: Cu-Catalyzed C -C -Coupling of Electron-Deficient SF -Alkynes with Alkyl Iodides.

Narra S, Bacho M, Hattori M, Shibata N Adv Sci (Weinh). 2023; 11(11):e2306554.

PMID: 38161224 PMC: 10953538. DOI: 10.1002/advs.202306554.

Fluoroalkylated hypervalent sulfur fluorides: radical addition of arylchlorotetrafluoro-λ-sulfanes to tetrafluoroethylene.

Yasuo E, Aikawa K, Nozaki K, Okazoe T Chem Sci. 2023; 14(43):12379-12385.

PMID: 37969576 PMC: 10631236. DOI: 10.1039/d3sc04837c.

Strain-Release Pentafluorosulfanylation and Tetrafluoro(aryl)sulfanylation of [1.1.1]Propellane: Reactivity and Structural Insight.

Kraemer Y, Ghiazza C, Ragan A, Ni S, Lutz S, Neumann E Angew Chem Int Ed Engl. 2022; 61(48):e202211892.

PMID: 36137228 PMC: 9828730. DOI: 10.1002/anie.202211892.