Colouring Crystals with Inorganic Nanoparticles
Overview
Affiliations
A simple, one-pot method is presented whereby gold nanoparticles coated with a zwitterionic diblock copolymer are incorporated within single crystals of calcite. This may provide a versatile alternative to dyeing crystal with organic molecules and could be extended to create a series of new nanocomposite crystals with novel properties.
Positively Charged Additives Facilitate Incorporation in Inorganic Single Crystals.
Nahi O, Broad A, Kulak A, Freeman H, Zhang S, Turner T Chem Mater. 2022; 34(11):4910-4923.
PMID: 35722202 PMC: 9202304. DOI: 10.1021/acs.chemmater.2c00097.
Micron-sized biogenic and synthetic hollow mineral spheres occlude additives within single crystals.
Marzec B, Walker J, Jhons Y, Meldrum F, Shaver M, Nudelman F Faraday Discuss. 2022; 235(0):536-550.
PMID: 35388821 PMC: 9281370. DOI: 10.1039/d1fd00095k.
Nahi O, Kulak A, Kress T, Kim Y, Grendal O, Duer M Chem Sci. 2021; 12(28):9839-9850.
PMID: 34349958 PMC: 8293999. DOI: 10.1039/d1sc02991f.
Ptychographic X-ray tomography reveals additive zoning in nanocomposite single crystals.
Ihli J, Levenstein M, Kim Y, Wakonig K, Ning Y, Tatani A Chem Sci. 2020; 11(2):355-363.
PMID: 32874489 PMC: 7442293. DOI: 10.1039/c9sc04670d.
Hydroxyl-rich macromolecules enable the bio-inspired synthesis of single crystal nanocomposites.
Kim Y, Darkins R, Broad A, Kulak A, Holden M, Nahi O Nat Commun. 2019; 10(1):5682.
PMID: 31831739 PMC: 6908585. DOI: 10.1038/s41467-019-13422-9.