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Catalytic Enantioselective Dibromination of Allylic Alcohols

Overview
Journal J Am Chem Soc
Specialty Chemistry
Date 2013 Aug 20
PMID 23952929
Citations 27
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Abstract

A new dibromination reaction involving the combination of dibromomalonate as the bromonium source and a titanium bromide species as the bromide source has been developed. Enantioselective catalysis has been achieved through apparent ligand acceleration by a tartaric acid-derived diol.

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