» Articles » PMID: 23786307

Using Optical Tweezers for the Characterization of Polyelectrolyte Solutions with Very Low Viscoelasticity

Overview
Journal Langmuir
Specialty Chemistry
Date 2013 Jun 22
PMID 23786307
Citations 1
Authors
Affiliations
Soon will be listed here.
Abstract

Recently, optical tweezing has been used to provide a method for microrheology addressed to measure the rheological properties of small volumes of samples. In this work, we corroborate this emerging field of microrheology by using these optical methods for the characterization of polyelectrolyte solutions with very low viscoelasticity. The influence of polyelectrolyte (i.e., polyacrylamide, PAM) concentration, specifically its aging, of the salt concentration is shown. The close agreement of the technique with classical bulk rheological measurements is demonstrated, illustrating the advantages of the technique.

Citing Articles

Microrheology with optical tweezers: measuring the relative viscosity of solutions 'at a glance'.

Tassieri M, Del Giudice F, Robertson E, Jain N, Fries B, Wilson R Sci Rep. 2015; 5:8831.

PMID: 25743468 PMC: 4894396. DOI: 10.1038/srep08831.

References
1.
Pommella A, Caserta S, Guida V, Guido S . Shear-induced deformation of surfactant multilamellar vesicles. Phys Rev Lett. 2012; 108(13):138301. DOI: 10.1103/PhysRevLett.108.138301. View

2.
Carrillo J, Dobrynin A . Layer-by-layer assembly of polyelectrolyte chains and nanoparticles on nanoporous substrates: molecular dynamics simulations. Langmuir. 2011; 28(2):1531-8. DOI: 10.1021/la203940w. View

3.
Sun B, Mutch S, Lorenz R, Chiu D . Layered polyelectrolyte-silica coating for nanocapsules. Langmuir. 2005; 21(23):10763-9. DOI: 10.1021/la0513297. View

4.
van den Ende D, Purnomo E, Duits M, Richtering W, Mugele F . Aging in dense suspensions of soft thermosensitive microgel particles studied with particle-tracking microrheology. Phys Rev E Stat Nonlin Soft Matter Phys. 2010; 81(1 Pt 1):011404. DOI: 10.1103/PhysRevE.81.011404. View

5.
Caserta S, Guido S . Vorticity banding in biphasic polymer blends. Langmuir. 2012; 28(47):16254-62. DOI: 10.1021/la303232w. View