A General Method to Diverse Cinnolines and Cinnolinium Salts

Overview

Journal Chemistry

Specialty Chemistry

Date 2013 Apr 5

PMID 23553746

Citations 9

Authors

Dongbing Zhao

Qian Wu

Xiaolei Huang

Feijie Song

Taiyong Lv

Jingsong You

Affiliations

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Abstract

Rhodium catalysis: A highly efficient and general method has been established to prepare cinnolines, cinnolinium salts, and polycyclic cinnolinium salts through the rhodium(III)-catalyzed oxidative C-H activation/cyclization of azo compounds with alkynes (see scheme). Key features of this methodology include the unprecedented capacity to create both cinnoline and cinnolinium frameworks.

Citing Articles

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Sc(OTf)-Mediated [4 + 2] Annulations of -Carbonyl Aryldiazenes with Cyclopentadiene to Construct Cinnoline Derivatives: Azo-Povarov Reaction.

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El-Marrouki D, Touchet S, Abdelli A, Mrabet H, Efrit M, Gros P Beilstein J Org Chem. 2020; 16:1722-1731.

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Bai D, Xia J, Song F, Li X, Liu B, Liu L Chem Sci. 2019; 10(14):3987-3993.

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