γ-Selective Directed Catalytic Asymmetric Hydroboration of 1,1-disubstituted Alkenes

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2012 Nov 13

PMID 23145431

Citations 14

Authors

Sean M Smith

Gia L Hoang

Rhitankar Pal

Mohammad O Bani Khaled

Liberty S W Pelter

Xiao Cheng Zeng

James M Takacs

Affiliations

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Abstract

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).

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