Efficient Generation of Stable Adducts of Si(II) Dihydride Using a Donor-acceptor Approach

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2011 Dec 20

PMID 22179178

Citations 4

Authors

S M Ibrahim Al-Rafia

Adam C Malcolm

Robert McDonald

Michael J Ferguson

Eric Rivard

Affiliations

Soon will be listed here.

Abstract

A stable Si(II) dihydride complex, IPr·SiH(2)·BH(3) (IPr = [(HCNDipp)(2)C:]; Dipp = 2,6-(i)Pr(2)C(6)H(3)), was synthesized and preliminary reactivity involving this source of encapsulated silylene is reported.

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